The [Fe(NO)(‘XS4’)] species (X S, NH) are paramagnetic (μeff=2.36 and 2.13 BM respectively); all other complexes are diamagnetic and were characterized by spectroscopic means and elemental analyses. [Fe(NO)(‘NHS4’)] crystallizes in space group P21/c with a=1262.7(6), b=744.9(...
A technique (functional magnetic resonance imaging) that provides high resolution, noninvasive imaging of neural activity detected by a blood oxygen level-dependent signal (haemoglobin is diamagnetic when oxygenated but paramagnetic when deoxygenated) based on the increase in blood flow to the local vasc...
and since for the N-terminal residues no unique structure is to be expected, the analysis of the paramagnetic enhancement (PRE) was only done in a qualitatively manner by comparing differences in cross peak volumes of the paramagnetic and diamagnetic sample (after reduction of the spin label). ...
probing diamagnetic dopants in TiO2 environment of boron dopant in B,N–codoped by electron paramagnetic resonance spectroscopy. anatase TiO2 J. Am. Chem. 10. Nguyen-Phan, T. D. et al. Synthesis of hierarchical rose bridal bouquet-and humming-top-like dependent degradation efficiency of dye. ...
(J Chem Theory Comput 2:1360–1369,2006) exhibit large contraction errors for one-bond couplings, but in their uncontracted form they perform better than the ccJ-pVXZ basis sets. For multi-bond couplings, however, diffuse functions should be used, and when including these the two hierarchies...
2OG 2-oxoglutarate ACV l-δ-(α-aminoadipoyl)-l-cysteinyl-d-valine BTFA 3-bromo-1,1,1-trifluoroacetone CV column volume DEER double electron–electron resonance DSBH double-stranded β-helix EPR electron paramagnetic resonance IPN isopenicillin N IPNS isopenicillin N synthase IPSL 3-(2-iodo...
6G), with a decrease in intensity in the presence of 0.1 eq of MTSL-tagged NGAL similar to the intensity decrease observed in presence of 0.2–0.3 eq of diamagnetic NGAL. This clearly indicates that hLCN2-R-NTD experiences paramagnetic relaxation enhancement due to the spatial proximity with ...
These are the trades consistent of a transition from a paramagnetic to a long-range magnetically-ordered state. The magnetic transition temperature can be determined from the infection point. However, unlike a material with a single magnetic transition, Mn3[Cr(CN)6]2·10H2O displays a slight S...
Considering there are 2 [M(H2O)5(β-HAla)]2+ cations per formula unit, the value of c is twice the concentration of the compound in the solution. The χp values [cm3mol−1] are molar susceptibilities corrected for diamagnetic contribution to the susceptibility in the sample. 𝜒p=...
Diamagnetic corrections from the sample, mother solution, and sample holder were introduced [24]. Continuous Shape Measure Analysis for the coordination sphere of each metal complex was performed using a SHAPE software [25]. 3.4. Synthetic Procedures Synthesis of 1. The 14.7 mg (0.06 mmol) of ...