RUTHENIUM CARBONYL HYDRIDESX-RAY STRUCTURECLUSTER CHEMISTRYDYNAMIC BEHAVIORHYDROGEN-ATOMS(MU-H)4RU4(CO)10(DIPHOS)RU3(CO)12LIGANDSThe crystal and molecular structures of Ru-4(mu-H)(4)(CO)(11)(CNBut) (2), obtained with Ru-4(mu-H)(4)(CO)(10)(CNBut)(2) by hydrogenation of Ru-5(mu...
(18)],respectively.Thestructure of complex 16centre dot0.5cyclohexane has been determin4ed by X-ray crystallography.The Ru-Ru bond distance in the [Ru_2(#mu#-HNOCC_4H_3S)_4(thf)_2]~+ unit is 2.286(2)A.Amagnetic study,in the 2-300K temperature range,of thecompounds is described....