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The spirocyclic part consisting of an α-acylated tetronic acid and a multisubstituted cyclohexene embedded in versipelostatin, a novel GRP78/Bip molecular chaperone downregulator, has been synthesized in enantiomerically pure form. The asymmetric synthesis of the targeted spiro[4.5]-1-oxa-7-decen-...
I(0)/C gave an estimate of apparent molecular mass of solute, where C is the protein concentration of HSP60 or GroEL. After a circular average of the two-dimensional data and buffer subtractions, the pair distribution function P(r) was calculated using the GNOM program [48]. The maximum...
International Journal of Molecular Sciences Article Diversity-Oriented Synthesis of a Molecular Library of Immunomodulatory α-Galactosylceramides with Fluorous-Tag-Assisted Purification and Evaluation of Their Bioactivities in Regard to IL-2 Secretion Yeng-Nan Chen 1,† , Jung-Tung Hung 2,†, Fan...