At room temperature, benzene adsorbs in a molecular state. The ARUPS are consistently interpreted in terms of a C6v symmetry of the adsorbate complex. This indicates that the benzene molecule is essentially undistorted at the surface and adsorbed in a planar geometry, i.e. with the aromatic ...
Structural Consequences of the Substituent Nonsymmetry on the Geometry of the Benzene Ring. Analysis of the Molecular Geometry of Diazo-Derivatives of BenzeneAnalysis of the precisely measured geometry (retrieved from the CSD) of 21 di... TM Krygowski,R Anulewicz,PC Hiberty - 《Journal of Org...
ChemInform Abstract: THE GEOMETRY OF THE PHENYL RING IN SUBSTITUTED BENZENE MOLECULES. A MOLECULAR ORBITAL APPROACHdoi:10.1002/chin.198023063J. A. CAMPOSJ. CASADOM. A. RIOSChemischer Informationsdienst
Crystal structure and molecular geometry of tetraphenylphosphonium π-cyclopentadienylbis-(1,2-dicyanoethylene-1,2-dithiolato)molybdenum, [Ph4P+][(π-C5H5)... The crystal and molecular structure of tetraphenylphosphonium π-cyclopentadienylbis-(1,2-dicyanoethylene-1,2-dithiolato)molybdenum, [Ph4P+]...
A topological analysis of the molecular charge density was performed using Bader's method to gain insight into the dominant intra- and intermolecular interactions in this compound. In particular, the effects of the substituents on the observed distortions of the benzene ring were investigated as well...
T Cvita, J M Hollas and G H Kirby Mol. Phys. 19 305 (1970)Cvitas,̌ T.; Hollas, J. M.; Kirby, G. H. Interpretation of Rotational Constants of the First Singlet Excited State of Substituted Benzenes in Terms of Molecular Geometry. Mol. Phys. 1970, 19, 305-316....
(C5H5)2ZrCl2 and AlCl3 react in benzene or toluene to form an adduct that under certain conditions readily dissolves in benzene or toluene to form a binary liquid liquid phase system (“liquid clathrate”), the denser of which contains the Cp2Zr moiety and possesses stoichiometry 16.3 and 15.4...
Crystal Structure of Poly[(2,6-di(2',4'-dicarboxylphenyl)pyridine-κ4 0:0':0":0"')-(μ2-l,4-bis (l-imidazolyl)benzene-κ2N:N') cobalt(II)], C39H... [Objective] The paper was to synthesize a new structure of metal organic framework, and to provide new materials for plant ...
Evidence for resonance-assisted hydrogen bonding from crystal-structure correlations on the enol form of the ??-diketone fragment The geometry variations caused by inter- and intramolecular hydrogen bond (HB) formation on the molecular fragment acacH (HOCR=CR-CR=O) contained in the enol form of...
In the title compound, C16H15BrN2O4·H2O, the hydrazide molecule is nearly planar, with a largest deviation from the mean plane through the non-H atoms of 0.106 (4) Å and a dihedral angle between the benzene rings of 1.98... PR Reshma,M Sithambaresan,MRP Kurup - 《Acta...