However, the presence of Au-n cluster also induces deformation energy toward the MOF-801 structure. The binding sites of Au-n cluster on the surface of MOF-801 has been assessed using the independent gradient model to unveil possible intermolecular forces between the host and guest system. The...
However, not only the composition and crystal structure of MOFs is crucial for most applications. The size of particles and the concentration of defects could have a significant impact on the properties of resulting materials. The concept of coordination modulation could be used for intelligent ...
(Rh110) molecules and porous MOFs, could not only overcome the shortcomings of hydrophobicity of dye molecules and preserve its fluorescent properties perfectly, but also facilitate the interaction between nitrite and fluorescent recognition sites thanks to the open structure and good stability of porous...
MXenes优点 ①MXenes具有优异的导电性(电导率10^5 S/m)、电导率达到部分金属级别,具体见表1。 表1 MXenes与其它材料电导率比较 材料 电导率(S/m) 备注 银 6.3X10^7 导电性最好的金属 铜 5.9X10^7 常用导线 铝 3.7X10^7 常用导线 镁 2.2X10^7 ...
Metal–organic frameworks (MOFs) are porous crystalline materials constructed from metal ions connected in three-dimensional structure by organic ligands. They have attracted significant interest due to their high porosity, structural versatility, and high stability. MOFs have been widely investigated for ...
However, their inherent microporous structure poses challenges in achieving a higher adsorption capacity. Defect engineering is considered a simple method to create hierarchical MOFs with larger pores. Here, we employed l-aspartic acid as a mixed linker to bind Zr4+ clusters in competition with ...
In this context, Metal–organic frameworks (MOFs) have garnered considerable interest due to their unique structure and intrinsic porosity. Here, MOF 801 was synthesized using two different methods: solvothermal and green room temperature synthesis. Comprehensive characterization indicated the formation of...
For the first time, two configurations of compact MOF-801 bed, namely, grains glued to the surface of a metal support and thin adsorbent coatings, are prepared, and their porous structure is characterized. The water adsorption dynamics is compared with a common loose grains configuration. The ...
The maximum reflectance-peak wavelength of it shifted obviously in the range of 20%-90% under varying %RH levels, due to the highly moisture-sensitive MOF-801 film in the 1DPC structure. It was demonstrated that the linear spectrum sensitivity of the MOF-801/TiO2 %RH 1DPC sensor is ...
The maximum reflectance-peak wavelength of it shifted obviously in the range of 20%-90% under varying %RH levels, due to the highly moisture-sensitive MOF-801 film in the 1DPC structure. It was demonstrated that the linear spectrum sensitivity of the MOF-801/TiO2 %RH 1DPC sensor is ...