Alternating bimetallic Na/Mn covalent and ionic chainsBergN.JonesL.CRYSTENGCOMM
We report the synthesis and full characterisation of a family of chains each exhibiting an alternating [M–Na–M–]n(M = Mn3+or Fe3+) 1-D topology linkedviathe 2,2′-biphenol ligand along with various N-donor co-ligands such as pyridine, 3-picoline and 2,2-bipyridine. The chains [...
Ionic and covalent mixed-metal complexes by reaction of transition metal M H acids (M=Mo, Mn, Fe, Co) with [Ir(PMe 3 ) 4 CH 3 ] or [Rh(PMe 3 ) 3 CH 3 ] and structurally related Rh M and Ir M heterobimetallics (M=Mn, Fe, Ru)...
Ionic and covalent mixed-metal complexes by reaction of transition metal M H acids (M=Mo, Mn, Fe, Co) with [Ir(PMe3)4CH3] or [Rh(PMe3)3CH3] and structurally related Rh M and Ir M heterobimetallics (M=Mn, Fe, Ru)Oxidative additionAlkylhydrido complexesMetal&z.sbnd...
Alternating bimetallic Na/Mn covalent and ionic chainsElectronic supplementary information (ESI) available: Solid State and Solution Characterisation. CCDC reference numbers 778267-778270. For ESI and crystallographic data in CIF or other electronic......