Metal sulphate compounds, especially calcium sulphate, lanthanum sulphate and/or cerium sulphate, compounds are also useful. The mixed metal compounds have a phosphate binding capacity of at least 30%, by weight, based on the test methods 1, 2 or 3, described in the specification, over a pH...
The resulting anionic compound will chelate to copper(II), cobalt(II), dioxouranium(VI), and thorium(IV) through the oxygens to give mixed metal compounds (PtCl[OP(OR)2]2L}nM (n = 2, R = Me, L = PEt3, M = Cu, UO2 and L = PPh3, M = Co; n = 2, R = Ph, L = PEt3...
Two highly reactive heterodinuclear bisμ-oxo complexes were prepared by combining mononuclear peroxo species with reduced metal precursors at 80 °C and were identified by UV-vis, EPRNMR, and resonance Raman spectroscopy, with corroboration in the case of the CuPd system from density functional ca...
Cuprous oxide (Cu2O), an earth-abundant, low-cost metal-oxide semiconductor, has received enormous attention for its CO2 reduction ability in aqueous media by photochemical, photoelectrochemical and electrochemical methods. An unresolved problem with all
Mixed metal hydroxides comprising amorphous aluminum hydroxide, and their preparation and use Mixed metal hydroxides comprising amorphous aluminum hydroxide, and their preparation and useThe present invention relates to a particulate mixed metal hydroxide that includes nickel, cobalt and aluminium. The ...
This paper presents a survey of the study and development of metal clusters. 本文对金属簇合物的研究进展作了概述,着重介绍了几种近几年合成的具有新结构形式和新成键方式的铁和钴等羰基簇合物,探讨了金属簇合物的研究趋势。 更多例句>> 补充资料:金属卤素簇合物 分子式:CAS号:性质: 以卤素为配体的金...
The placement of mixed building blocks at precise locations in metal–organic frameworks is critical to creating pore environments suitable for advanced applications. Here we show that the spatial distribution of mixed building blocks in metal–organic frameworks can be modulated by exploiting the differe...
Heating the mixed-metal cluster PhCCo2Ni(CO)6Cp with the diphosphine ligand 2,3-bis(diphenylphosphino)maleic anhydride (bma) in 1,2-dichloroethane proceeds by CO loss and formation of the cobalt-bridged cluster PhCCo2Ni(CO)4(η2-bma)Cp (2). The bma ligand is fluxional in solution and...
Structural flexibility is a critical issue that limits the application of metal-organic framework (MOF) membranes for gas separation. Herein we propose a mixed-linker approach to suppress the structural flexibility of the CAU-10-based (CAU = Christian-Al
THE SYNTHESIS OF A DINUCLEAR ANIONIC CARBONYL DERIVATIVE OF MANGANESE, (N(PPH3)2)(MN2(μ-PPH2)(CO)8), AND ITS REACTIONS WITH COMPLEXES OF GROUP 1B AND GROUP 8 METALS TO GIVE MIXED-METAL CLUSTERS: COMPARATIVE STUDY OF THE X-RAY CRYSTAL The combination of lithiated alkoxyallenes with carbo...