本文通过在MgTFSI2-MgCl2/DME电解液中引入电子不足的三(2,2,2-三氟乙基)硼酸酯(TFEB)添加剂,成功调控了电极-电解质界面,降低了MgF2和MgO在固体电解质界面(SEI)中的含量,从而改善了镁离子电池的性能。实验结果表明,使用TFEB添加剂的电解质可以使Mg//Mg电池在400小时内稳定循环,并且具有较小的极化电压。即使存...
本文通过在MgTFSI2-MgCl2/DME电解液中引入电子不足的三(2,2,2-三氟乙基)硼酸酯(TFEB)添加剂,成功调控了电极-电解质界面,降低了MgF2和MgO在固体电解质界面(SEI)中的含量,从而改善了镁离子电池的性能。实验结果表明,使用TFEB添加剂的电解质可以使Mg//Mg电池在400小时内稳定循环,并且具有较小的极化电压。即使存...
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Herein, a hybrid electrolyte MgCl_(2)/AlCl_(3)/Mg(TFSI)_(2) (MACT) in dimethyl ether (DME) is developed and exhibits excellent electrochemical performance. The high ionic conductivity (6.82 mS cm~(–1)) and unique solvation structure of [Mg_(2)(μ-Cl)_(2)(DME)_(4)]~(2+) ...
(2)/DME-TFEB electrolyte could cycle stably for over 400 h with a small polarization voltage of~150 mV.Even with the presence of 800 ppm H_(2)O,the electrolyte with TFEB additive could still preserve its good electrochemical performance.The optimized electrolyte also enabled stab...
The Mg-Mg symmetrical cell with modified Mg electrode exhibits lower overpotential (~0.25聽V) and interfacial impedance than bare Mg electrode in 0.5聽M聽Mg(TFSI) 2 /DME electrolyte. The voltage hysteresis in the Mg-S and Mg-Mo 6 S 8 batteries with the modified Mg anode is greatly ...
The thermodynamics and reaction pathway of sulfur cathode in MgTFSI 2 -DME electrolyte, as well as the associated kinetics are thoroughly investigated. The results here reveal that sulfur undergoes a consecutive staging pathway in which the formation and chain-shortening of polysulfide occur at early...
The thermodynamics and reaction pathway of sulfur cathode in MgTFSI2-DME electrolyte, as well as the associated kinetics are thoroughly investigated. The results here reveal that sulfur undergoes a consecutive staging pathway in which the formation and chain-shortening of polysulfide occur at early ...
The thermodynamics and reaction pathway of sulfur cathode in MgTFSI2–DME electrolyte, as well as the associated kinetics are thoroughly investigated. The results here reveal that sulfur undergoes a consecutive staging pathway in which the formation and chain‐shortening of polysulfide occur at early ...
本文通过在MgTFSI2-MgCl2/DME电解液中引入电子不足的三(2,2,2-三氟乙基)硼酸酯(TFEB)添加剂,成功调控了电极-电解质界面,降低了MgF2和MgO在固体电解质界面(SEI)中的含量,从而改善了镁离子电池的性能。实验结果表明,使用TFEB添加剂的电解质可以使Mg//Mg电池在400小时内稳定循环,并且具有较小的极化电压。即使存...