metal-organic frameworkspolymersstimulus responseMaterials that can recognize the changes in their local environment and respond by altering their inherent physical and/or chemical properties are strong candidates for future “smart” technology materials. Metal–organic frameworks (MOFs) have attracted a ...
Metal-organic frameworks (MOFs) are highly attractive materials because of their ultra-high surface areas, simple preparation approaches, designable structures, and potential applications. In the past several years, MOFs have attracted worldwide attention in the area of hydrogen energy, particularly for...
Metal-organic frameworks (MOFs) have emerged as a significant class of porous materials renowned for their well-defined structures and various applications in the last few decades. As a novel category of solid adsorbents, MOFs have overshadowed many traditional porous materials owing to their ...
Tailoring metal-organic frameworks for CO2 capture: The amino effect - Vitillo, Savonnet, et al.Vitillo, J.G.; Savonnet, M.; Ricchiardi, G.; Bordiga, S. Tailoring metal-organic frameworks for CO2 capture: The amino effect. Chemsuschem 2011, 4, 1281-1290....
solvation energyWe investigated which factors govern the critical steps of cation exchange in metal–organic frameworks by studying the effect of various solvents on the insertion of Niinto MOF‐5 and Cointo MFU‐4. After plotting the extent of cation insertion versus different solvent parameters, ...
organic frameworksphotochemistryEfforts to improve the overall efficiency of photoelectrochemical water splitting by promoting interfacial charge transfer and suppressing electron–hole recombination remain a challenge. Highly porous Co 3 O 4 @carbon derived from metal–organic frameworks was successfully ...
Soaking Ni2(dobdc) in sulfuric acid solutions at different pH values afforded new proton-conducting frameworks, H+@Ni2(dobdc). At pH 1.8, the acidified MOF shows proton conductivity of 2.2×10−2 S cm−1 at 80 °C and 95 % relative humidity (RH), approaching the highest...