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Some Friedel-Crafts-type protocols fall into this category, but suffer from limited substrate scope (electron rich arenes) and limited control over the reactive position on a given aromatic substrate. We envisioned that a neglected S-tetracovalent dialkoxyl alkyl aryl intermediate (Fig. 1f, see ...
46. 2 mol% loading of1-Crpromoted propargylation of aldehydes for both aromatic aldehydes with electron-donating and electron-withdrawing groups on the aromatic rings, furnishing the homopropargylic alcohols in 90–96% isolated yields with 91–99% ee after 12 h (Table2). When 1-...
I thought her Bacon and Egg beads were so cute that I kept the theme going. I used mixed metals: brass wire, copper and brass jump rings, brass chain and lots of dangles. I’ve been making Cork Pendant necklaces for a few months and kept looking for a cork that had a chicken or ...
Emboosed 3D Terne Metal Horse Key Chains for Gift (XDBG-277) Item key rings Process Stamping / die casting Material Iron, brass, zinc alloy, gold, silver, brass, iron, stainless steel/iron, aluminum alloy, soft PVC and more Size Any size & customer size T...