OzonolysisReaction mechanismsThe formation of ozonides (1,2,4-trioxolanes) from alkenes and ozone can be described as a succession of three [2+3] cycloadditions or cycloreversions involving primary ozonides (1,2,3-trioxolanes) and aldehyde or ketone oxides as decisive intermediates, all of ...
Ab initio study of the primary ozonide and its cleavage to the Criegee intermediate [J]. Journal of the American Chemical Society, 1976, 98(20): 6088-6092. DOI: 10.1021/ja00436a002.HIBERTY P C. Mechanism of ozonolysis. Ab initio study of the primary ozonide and its cleavage to the ...
What is Ozonolysis? Understand the Mechanism of Ozonolysis of Alkenes and Alkynes, the Oxidative and Reductive Workup in the Ozonolysis and about Ozone Cracking.
Correspondence to: Haizhou Dong, College of Food Science and Engineering, Shandong Agricultural university, Taian, People’ Republic of China. Email:haizhoudong@126.com Abstract Many studies have proved that ozone can decompose aflatoxins in peanuts, while polyphenols in peanut skins can also be destr...
Criegee mechanism of ozonolysisdoi:10.1007/978-3-662-04835-1_71Li, Jie Jack
Experimental distributions of the reaction paths of selected alkyl-substituted 1,2,3-trioxolanes to give (a) R1C+HOO- + R2CHO or (b) R1CHO + R2C+HOO- are compared with Mulliken overlap populations and with gross electron densities of the trioxolanes. In general, the preferential path of...
Hydroxyl-radical formation in the gas-phase ozonolysis of 2-methylbut-2-ene The origin of the anomalous result for the cyclohexane/2-methylpropane pair is not clear.doi:10.1029/98GL01588Marston, G. G Marston,McGill, C. D.,AR Rickard - 《Geophysical Research Letters》 被引量: 64发表: ...
Kinetics and mechanism of oxidation of ascorbic acid by manganese(III) in aqueous acidic perchlorate media 来自 Wiley 喜欢 0 阅读量: 19 作者:PELIZZETTI, E.,MENTASTI, E.,PRAMAURO, E.摘要: No abstract is available for this article.关键词: oxidation, dehydrogenation, ozonolysis ...
oxidation, dehydrogenation, ozonolysisstereochemistry (general, optical resolution)ChemInform is a weeklying Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInformof an article which was published elsewhere, please select a "Full ...
oxidation, dehydrogenation, ozonolysisNo abstract availabledoi:10.1002/chin.199222296R. L. KUCZKOWSKIDep. Chem., Univ. Michigan, Ann Arbor, MI 48109-1055, USAJohn Wiley & Sons, Ltd.ChemInformKuczkowski, R.L. (1992) Chem. Soc. Rev. 21 , 79–83....