Gibbs自由能差\Delta G^{0'}可通过电极电势改变。所以Marcu equation可以改写成下面的形式\Delta G^{\ddagger}=\frac{\lambda}{4} (1+\frac{F(E-E^{0})}{\lambda})^{2}。利用Marcus theory可以预测不同电压下,电极反应的活化能和反应速率如何随之改变,我们就能得到电流和电压的关系式。和传统的Butle ...
Marcus equationIn the late 1950s and early 1960s Rudolph A. Marcus developed a theory for treating the rates of ou…Sutin, Norman
a龙门石窟中间是一个大湖,记得去的时候湖中有个大莲花 Among the Longmen Grottoes is a great lake, remembered in the time Lake has a big lotus flower[translate] aThe Marcus equation, Eq. (1), 马库斯等式, Eq。(1),[translate]
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The Marcus equation for the electron-transfer rate is generalized to the form which is applicable to molecular models of the solvent. The rate constant is expressed in terms of the function phi(DELTAV), which describes the distribution of the electrostatic potential difference DELTAV between donor...
ChemInform Abstract: ON THE APPLICATION OF THE MARCUS EQUATION TO METHYL TRANSFER (SN2) REACTIONSheat of reactionNo abstract is available for this article.doi:10.1002/chin.198451088J. A. DODDJ. I. BRAUMANWILEY‐VCH Verlag GmbHChemischer Informationsdienst...
The microscopic reversibility of the rate constants given by the generalized Marcus equation which was recently presented by Tachiya has been proved. It is concluded that although in the original Marcus equation the energy gap is expressed in terms of thermodynamical free energy, there is no necessi...
3.还想请问下老师，这类反应算出来的自由能垒可不可以代入Eyring equation算反应速率常数？如果不行的话...
Marcus makes sure while you are treated like a personal friend, that professionalism is never removed from the equation. He simplifies your wishes for a website so that even a 10 year old can understand, then Marcus adds more service than you expect – been using his innovations since 2011 ...
在科学的殿堂里，Marcus理论犹如一盏明灯，照亮了电子转移的神秘路径，由Rudolph A. Marcus在1956年首次提出，其贡献于1992年赢得了诺贝尔奖的荣耀。这个理论细致区分了电子转移的内外两层，揭示了生物反应中电子传递的微妙差异。生物世界中的电子转移，大多遵循外层转移的路径，因为分子结构的限制往往阻碍了...