It then turns to the caloric properties of nonideal gases and derives the expressions for the internal energy and the specific heats.doi:10.1016/B978-0-12-384956-4.00012-4Nils DalarssonMariana DalarssonLeonardo GoluboviIntroductory Statistical Thermodynamics...
Thermodynamics. Study of temperature, heat and related macroscopic properties of objects and matter. Specifically macroscopic properties: temperature, pressure, heat, internal energy… Thermodynamic equilibrium: two systems are in thermodynamic equilibrium with each other, when they are in thermal contact an...
Therefore, we are not considering here any semi-classical or quantum gravity which apparently suggests thermodynamical properties even for a (singular) black hole. Having made such a clarification, we formulate a global first law of thermodynamics for an adiabatically evolving spherical perfect fluid. ...
In classical thermodynamics, entropy is defined in terms of macroscopic measurements and makes no reference to any probability distribution, which is central to the definition of information entropy. 在传统热力学中,熵被定义为对系统的宏观测定,并没有涉及概率分布,而概率分布是信息熵的核心定义。 LASER...
Volume 14 of Reviews in Mineralogy covers a short course about the relations among the microscopic structure of minerals and their macroscopic thermodynamic properties. Understanding the micro-to-macro relations provides a rigorous theoretical foundation for formulation of energy relations. With such a fou...
microscopic dynamics and macroscopic processes like viscosity; and, finally, the interest brought in statistical mechanics of irreversible processes by the ... S Viscardy 被引量: 2发表: 2005年 Thermodynamics and Statistical Mechanics Thermodynamics and Statistical Mechanics provides undergraduate chemistry ...
They also affect the nature of interaction with adsorbed species and this in turn can crucially affect the catalytic activity of the surface, its chemical activity, oxidation and corrosion. Finally, the solid surface has a macroscopic surface energy which is involved in the thermodynamics of wetting...
In the macroscopic part of the theory, a general prescription is given describing macrostates of the systems arbitrarily far from equilibrium in the language of generalized forces and fluxes of nonlinear irreversible thermodynamics. As a particular result, Onsager's reciprocity relations for the ...
Main attention is given to quasichemical models for the modeling of supramolecular ordering in mixtures, self-organized by H bonds, leading to a unified description of their physicochemical properties. We analyze the interrelations of thermodynamic functions (Gibbs energy, enthalpy, entropy), dielectric...
11、So in other words,macroscopicthermodynamic properties come straight out of our microscopic model of statistical mechanics.(换句话说,宏观的热力学性质可以,从微观模型,的统计力学得到。) 12、And actually just likemacroscopicthermodynamics, kinetics does take an empirical approach to the topic.(实际上就...