Metal-organic frameworksOrganic strutsPorous materialsSupramolecular chemistryOrganic struts incorporating macrocycles have been employed recently to construct extended metal-organic frameworks (MOFs), which opened up the possibility of forming hierarchically porous materials with two levels of porosity, i.e.,...
Porous materials, including covalent organic frameworks (COFs)13, metal organic frameworks (MOFs)14and porous organic cages (POCs)15, could potentially have their intrinsic cavities/apertures translated into membrane pores, but previous work has confronted the inevitable barriers of grain boundaries or ...
Ring-size controllable metallamacrocycles as building blocks for the construction of microporous metal-organic frameworks Presented here is a new strategy for the synthesis of metallamacrocycles (MC[n]) with different ring-size and guest selectivityviaintegrating a flexible tr... ZQ Jiang,GY Jiang,...
Ferrocene-Based Ureas as Multisignaling Receptors for Anionst. The synthesis of structurally new types of ferrocene-based ureas, in which the ferrocene moiety is simultaneously attached to two urea groups, have been pr... Otón,Francisco,Tárraga,... - 《Journal of Organic Chemistry》 被引量: ...
Two novel porous metal–organic frameworks (MOFs) with {M18(Hbtib)36} (M = Ni(II), Zn(II)) as the basic building unit, namely, [Ni(Hbtib)2]n (1) and [Zn(Hbtib)2·H2O]n (2) [H2btib = 4-((2-butyl-5-(2-carboxy-3-(thiophen-2-yl)prop-1-enyl)-1H-imidazol-1-yl)...
Wu, Xiao-YuanYu, Rong-MinLu, Can-ZhongCrystEngCommA microporous cationic metal-organic frameworkconstructed from metallamacrocycle-based nanocages: structures and luminescenceproperties. FANG Z-L,WU X-Y,YU R-M, et al. Crystengcomm . 2014
organic macrocyclescovalent polymerscovalent organic frameworksadsorptionenvironmental remediationAir, water, and soil pollution devastate countless ecosystems and deteriorate human health. Adsorption has commonly been used as a pollutant removal technique, but ongoing materials science research is still searching ...
A process for the preparation of a heterocyclic macrocycle-templated supramolecular metal organic material, the process comprising preparing a reaction mixture containing a metal, a heterocyclic macrocycle, and organic ligands and forming, in the reaction mixture, a heterocyclic macrocycle-templated metal ...
A microporous cationic metal-organic framework constructed from metallamacrocycle-based nanocages: structures and luminescence properties.doi:10.1039/c4ce01185fA novel metal-organic framework (MOF) {[Cu131Ll)10]⋅(OH)3(H2O)3}∞ (1) has been fabricated through in situ copper-mediated ring ...
Two different 2D layered metal–organic frameworks (MOFs) have been prepared using a hexanuclear manganese metallamacrocycle and an octanuclear manganese metallamacrocycle as supramolecular building blocks viaa simple change of the solvent used and/or addition of a templating agent. While the sheets ...