Usage Lithium iodide hydrate is used as a reagent for ester cleavage and decarboxylation and C-C bond forming reactions. It is also used as source of nucleophilic iodide, as a mild lewis acid, epoxide opening and as an additive for organometallic-mediated transformations....
Two-dimensional metal carbides/nitrides (MXexe) are widely used in catalysis [147], sensors [148], supercapacitors [149–151] and LIBs [152,153] due to their high electronic conductivity, remarkable chemical stability and Lewis-acidic properties [154–159]. Due to the synergistic effect, the ...
The 25Mg NMR area has been scarcely explored, however, some 25Mg NMR parameters (Table 6) have been detected for a number of organomagnesium compounds R2Mg, RMgX (R=alkyl, aryl, allyl, Cp, X=halide) and for their adducts with Lewis bases. Ranges of 25Mg chemical shifts for a number...
ChemInform Abstract: Lewis Base Adducts of Main Group 1 Metal Compounds. Part 7. The Lithium‐Coinage‐Metal Parallel: Novel Adducts of Lithium(I) Bromide and Iodide with 2,6‐Dimethylpyridinedoi:10.1002/chin.198915244organo‐lithium compounds...
Lithium-ion batteries are crucial to the future of energy storage. However, the energy density of current lithium-ion batteries is insufficient for future applications. Sulfur cathodes and silicon anodes have garnered a lot of attention in the field due
et al. Lewis acid–base interactions between polysulfides and metal organic framework in lithium sulfur batteries. Nano Lett. 14, 2345–2352 (2014). CAS Google Scholar Hassoun, J. & Scrosati, B. Moving to a solid-state configuration: a valid approach to making lithium-sulfur batteries ...
Lithium sulfide (Li2S) with as high as 66.7 at% Li represents a good candidate of Li-rich cathodes for developing anode-free cells with high energy. With a fully lithiated structure, the Li2S experiences negligible volume expansion upon cycling, particularly suitable for manufacturing high-loading...
Lewis base adducts of main group 1 metal compounds. 7. The lithium-coinage-metal parallel: novel adducts of lithium(I) bromide and iodide with 2,6-dimethylpyridinedoi:10.1002/chin.198915244Recrystallization of LiI and LiBr from 2,6-dimethylpyridine leads to the adducts (I) and (II) which ...
176 The coordination of Li(glyme)+ chelation must be strong enough to ensure stable complex cations, and the counter anions need to be a weak Lewis base, such as TFSI−, BETI−, or ClO4− (not NO3− or Tf−).80,176,180 In the local structure of SILs, one glyme molecule ...
Any critical field dosimetric survey, regardless of the methods used, should define the horizontal and vertical isopleths, both above and below ground level; it should determine the effects of terrain and vegetation in modifying the fine structure of the isopleths; it should measure exposure to ...