STRUCTURAL FEATURES OF LITHIUM-OXYGEN BOND RETRIEVED FOR IONIC CRYSTALS FROM CAMBRIDGE STRUCTURAL DATABASE AND INORGANIC STRUCTURAL DATA BASEK. WozniakT. KrygowskiPolish Journal of Chemistry
Lithium oxide (Li2O) is one of simplest ionic oxides and it is isoelectronic to H2O. Two lithium atoms will each give one electron to the oxygen atom. forms the ionic bond between lithium and oxygen. The formula for lithium oxide is Li2O. Lithium oxide is very corrosive. It reacts with ...
Due to the strong hybridization between boron and oxygen, Li3B11O18 has a higher thermodynamic oxidation limit of 4.45 V. First−principles calculations demonstrate that Li3B11O18 has both better stability with oxide cathodes as well as sulfide SSEs [211]. As opposed to the metal oxide ...
Organic liquid electrolytes (LEs) have been widely used for conventional LBs due to their high ionic conductivities and their excellent and stable interfacial wettabilities7. However, the ethers and carbonate solvents commonly used in LBs have low boiling points and high flammability8,9. When chroni...
It should be noted that carbonaceous materials usually have oxygen-containing surface groups, which are reduced during the first polarization processes in solutions. In general, the surface films on lithium and lithiated surface groups grow by the continuous reactions between the active mass and ...
(PLIBs), such as metal/sulfur, metal/air or metal/oxygen, or “post-lithium technologies” (systems without Li), which are based on alternative single (Na+, K+) or multivalent ions (Mg2+, Ca2+), are currently being studied intensively. From today’s point of view, it seems quite ...
Poly(ethylene glycol) (PEG), which can effectively transfer lithium ions by coordinating with lithium ions using their lone-pair electrons on the oxygen of the ether groups51–53, was further grafted onto this UPy-functionalized PAA as an ion-conducting group, thereby forming poly(acrylic ...
. The results show that the lithium atoms in the Li2Snspecies can bond with the oxygen atoms on the surface of polar SiO2or S-containing SiO2, while the sulfur atoms (Li2Sn) can interact with silicon atoms. Thus, the adsorption energies of Li2Snspecies on the SiO2and S-containing SiO2...
Conventional 1D inert materials are mainly metal oxide nanowires, such as Y2O3[135], TiO2[136,137], CeO2[138], and Al2O3[30]. Cui et al. reported a CSE containing Y2O3-doped ZrO2(YSZ) nanowires with positively charged oxygen vacancies [135...
Lithium ion has a hard Lewis acidity and thus strong affinity toward hard Lewis bases, such as oxygen- or nitrogen-containing ligands. These ligands can activate lithium compounds by deaggregation and electron donation; therefore, the use of chiral ligand enables asymmetric reactions by the ...