一文提到了一个非常重要的概念,配体加速的催化(LAC, Ligand Accelerated Catalysis)。这是 Sharpless 教授在 1995 年发表在《德国应用化学》杂志(Angew. Chem. Int. Ed. ,1995, 34, 1059)上的,根据论文的共同作者 C. Bolm 教授介绍,他们当时花了好几年的时间写成此文,在成文过程中,Sharpless 教授征求了很多化...
A practical consequence is the discovery of ligand-accelerated catalysis (LAC). Thus, an existing catalyzed process is improved by the addition of a specific ligand, which leads to a faster, "ligand-accelerated" reaction. Both homogeneous and heterogeneous catalysts are known to exhibit this ...
Paul K. Fraser,Simon Woodward.Strong ligand accelerated catalysis by an Arduengo-type carbene in copper-catalysed conjugate addition[J]. Tetrahedron Letters .2001(14)Fraser, P. K,Woodward, S.Strong ligand accelerated catalysis by an Arduengo-type carbene in copper-catalysed conjugate addition. ...
Copper catalysis 1. Introduction Vinyl nitriles are among the most privileged motifs prevalent in pharmaceuticals, agrochemicals, and functional materials [1], [2]. Both anti-HIV drug Rilpirine and Parkinson's disease drug Entacapone bear a crucial vinyl nitrile moiety. Moreover, acrylonitrile, the...
Capturing the dynamic processes of biomolecular systems in atomistic detail remains difficult despite recent experimental advances. Although molecular dynamics (MD) techniques enable atomic-level observations, simulations of “slow” biomolecular process
一文提到了一个非常重要的概念,配体加速的催化(LAC, Ligand Accelerated Catalysis)。这是 Sharpless 教授在 1995 年发表在《德国应用化学》杂志(Angew. Chem. Int. Ed. ,1995, 34, 1059)上的,根据论文的共同作者 C. Bolm 教授介绍,他们当时花了好几年的时间写成此文,在成文过程中,Sharpless 教授征求了很多...
A practical consequence is the discovery of ligand-accelerated catalysis (LAC). Thus, an existing catalyzed process is improved by the addition of a specific ligand, which leads to a faster, "ligand-accelerated" reaction. Both homogeneous and heterogeneous catalysts are known to exhibit this ...
Ligand-accelerated catalysis of the ullmann conden- sation: application to hole conducting triarylamines. J Org Chem 1999;64: 670e4.Goodbrand, H. B,Hu, N-X.Ligand-Accelerated Catalysis of the Ullmann Condensation: Application to Hole Conducting Triarylamines. J. Org. Chem . 1999...
Goodbrand H B,Hu N X.Ligand-accelerated Catalysis of the Ullmann Condensation: Application to hole Conducting Triarylamines. Journal of Organic Chemistry . 1999Goodbrand H B,Hu N X.Ligand-accelerated catalysis of the Ullmann condensation: application to hole conducting triarylamines.J. Org. Chem. ...
Metal- and Ligand- Accelerated Catalysis of the Baylis-Hillman Reaction. J. Org. Chem. 1998, 63, 7183-7189.Aggarwal , V. K. ; Mereu , A. ; Tarver, G. J. McCague , R. Metal- and ligand-accelerated catalysis of the Baylis–Hillman reaction . J. Org. Chem. 1998 , 63 , 7183 ...