Three aspects of the reaction of LiAlH4 in \\{HMPA\\} with oximes have been studied: the mechanism of the conversion of ketoximes into ketones, application of this reaction to the selective reduction of enones to ketones via the ene-oxime, and the conversion of aldoximes to either nitriles...
( 1a ) trans -[Fe(H) 2 ( η 2 -dppm) 2 ] ( 2 ) and trans -[Fe(H)(Cl)( η 2 -dppm) 2 ] ( 3 ), depending upon the reaction conditions. The trans octahedral structures, with chelating dppm ligands, of 1a and 2 have been established by X-ray crystallography. Compound 2 ...
desorption capacity (mass fraction) of 8.0%. The unknown Ti x+ containing compound forms during thermal desorption of the composite, which promotes effectively the synergetic dehydrogenation of LiAlH4 and MgH2. In addition, the dehydrogenation activation energy E a of the composite doped with ...
ChemInform Abstract: First Observation of a C‐CN Bond Cleavage During the Reduction of a Nitrile with LiAlH4: A SET Reaction?reduction, hydrogenationbridged compoundsChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading ...
ChemInform Abstract: First Observation of a C-CN Bond Cleavage During the Reduction of a Nitrile with LiAlH4: A SET Reaction?reductionhydrogenationbridged compoundsChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals....
In Step 2, Li3AlH6 decomposes via an endothermic reaction with a ∆H of 25 kJ·mol−1 H2 [6]. Hence the regeneration of Li3AlH6 from LiH and Al can be considered thermodynamically feasible. The last decomposition occurring at temperatures higher than 400 ◦C precludes this step from ...