Furthermore, photolysis of 2 under pressure of CO2 affords the first persistent SiO2–CO2 cycloadduct 3, presenting a Si2O4‐like structure, which is stabilized by a Lewis donor–acceptor type ligand. As predic
Tungsten nitride films were deposited on heated substrates by the reaction of vapors of tungsten bis(alkylimide)bis(dialkylamide) and a Lewis base or a hydrogen plasma. For example, vapors of tungsten bis(tert-butylimide)bis(dimethylamide) and ammonia gas supplied in alternate doses to surfaces...
Chojnowski, “Hydride Tranfer Ring-Opening Polymerization of a Cyclic Oligomethylhydrosiloxane. Route to a Polymer of Closed Multicyclic Structure”, Macromolecules, 2012, pp. 2654-2661, vol. 45. Chojnowski, “Oligomerization of Hydrosiloxanes in the Presence of Trisborane”, Macromolecules, 2006, ...
silicon dioxideThe donor-stabilized sila--lactone 1 reacts with CO2 via a remarkable reversible [2+2]-cycloaddition reaction to form the spiro-cyclic silicon carbonate derivative 2. Furthermore, photolysis of 2 under pressure of CO2 affords the first persistent SiO2-CO2 cycloadduct 3, presenting ...