Furthermore, photolysis of 2 under pressure of CO2 affords the first persistent SiO2–CO2 cycloadduct 3, presenting a Si2O4‐like structure, which is stabilized by a Lewis donor–acceptor type ligand. As predicted by theoretical calculations, in marked contrast to the thermodynamically stable SiO2...
Tungsten nitride films were deposited on heated substrates by the reaction of vapors of tungsten bis(alkylimide)bis(dialkylamide) and a Lewis base or a hydrogen plasma. For example, vapors of tungsten bis(tert-butylimide)bis(dimethylamide) and ammonia gas supplied in alternate doses to surfaces...
silicon dioxideThe donor-stabilized sila--lactone 1 reacts with CO2 via a remarkable reversible [2+2]-cycloaddition reaction to form the spiro-cyclic silicon carbonate derivative 2. Furthermore, photolysis of 2 under pressure of CO2 affords the first persistent SiO2-CO2 cycloadduct 3, presenting ...