reported in 2008 the isolation of the silicon complex Si2(NHC)2 which has a trans-planar arrangement of the CSiSiC moiety featuring a Si=Si double bond. A similar structure was found by us for the heavier homoloeues Ge2(NHC)2 and Sn2(NHC)2. Theoretical studies suggest that the NHC→...
molecules Article Silyl Ketene Acetals/B(C6F5)3 Lewis Pair-Catalyzed Living Group Transfer Polymerization of Renewable Cyclic Acrylic Monomers Lu Hu, Wuchao Zhao, Jianghua He * and Yuetao Zhang * ID State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin ...
4.3.2 Summary of Advice 4.3.3 Further advice 4.3.4 Structure of the Report 4.3.5 Computer Code General requirements Degree of original work required and plagiarism Documentation Word limit Code style" + ] + }, + { + "cell_type": "markdown", + "metadata": {}, + "source": [ + "...
Furthermore, photolysis of 2 under pressure of CO2 affords the first persistent SiO2–CO2 cycloadduct 3, presenting a Si2O4‐like structure, which is stabilized by a Lewis donor–acceptor type ligand. As predicted by theoretical calculations, in marked contrast to the thermodynamically stable SiO2...
Furthermore, photolysis of 2 under pressure of CO2 affords the first persistent SiO2–CO2 cycloadduct 3, presenting a Si2O4‐like structure, which is stabilized by a Lewis donor–acceptor type ligand. As predicted by theoretical calculations, in marked contrast to the thermodynamically stable SiO2...
Furthermore, photolysis of 2 under pressure of CO2 affords the first persistent SiO2-CO2 cycloadduct 3, presenting a Si2O4-like structure, which is stabilized by a Lewis donor-acceptor type ligand. As predicted by theoretical calculations, in marked contrast to the thermodynamically stable SiO2 ...