Crystal data are reported for [Cu(PPh3)2Cl]·0.5C6H6, [Cu(PPh3)2l], [Au(PPh3)2Cl](unsolvated), [Au(PPh3)2Br], and [Au(PPh3)2l]. In each structure the PPh3 ligands adopt an eclipsed conformation about M–P with respect to M–X, with X–M–P–C(11) conformational angles ...
What is the Lewis dot structure of P?Lewis Dot Diagram:The Lewis diagram is made by the means of solid dots, and it expresses the two kinds of electron pairs, the lone pairs along with the bonding electron pairs. The electronic configuration is desired for arranging the bond pairs and ...
Crystal data are reported for [Cu(PPh3)2Cl]·0.5C6H6, [Cu(PPh3)2l], [Au(PPh3)2Cl](unsolvated), [Au(PPh3)2Br], and [Au(PPh3)2l]. In each structure the PPh3 ligands adopt an eclipsed conformation about M–P with respect to M–X, with X–M–P–C(11) conformational angles ...
Alkylation of [(η5-C5H5)Ru(PPh3)(CNtBu)H] (1) with Ph3CPF6, Et3OBF4, or Me3OBF4 leads to formation of the dimeric salts {[(η5-C6H6)Ru(PPh3)(CNtBu)]2(μ-H)}PF6 (2) and {(n5-C5H5)Ru(PPh3)-(CNtBu)]2(μ-H)}BF4 (3), respectively, with low diastereoselectivity. ...
The Crystal and Molecular Structure of Dichlorobis(2-pyridinethiolato)tin(IV) The crystal and molecular structures of dichlorobis(2-pyridinethiolato)tin(IV) have been determined by X-ray analysis. The crystal belongs to the triclinic system: a=8.340(8), b=12.456(7), c=7.178(3) , α=86.46...
structure elucidationAttempted synthesis of the donor゛cceptor complex (BDI)Ca+←AlI(BDI) complex by reaction of (BDI)Ca+ in the form of its B(C6F5)4ˉ salt with (BDI)AlI in benzene led to dearomatization of the solvent and formation of (BDI)Ca+(C6H6)AlIII(BDI) (BDI = CH[C(CH3)...
It is important that the proton transfer, PT, process related to the hydrogen bond, HB, may be also discussed in terms of the structure-correlation method. For example, PT in O-H···O hydrogen bonds was analysed since -C=O···H-O-C- fragments taken from different crystal structures...
It was found that the strength of interaction increases with the increase of the atomic number of the tetrel element and that for heavier tetrel elements the ZFH3 tetrahedral structure is more deformed towards the structure with the planar ZH3 fragment. The results of calculations show that the ...