ChemInform Abstract: Preparation and Properties of (M(S2N2H)Cl(L)) (M: Pt, L: PMe2Ph or C2H4; M: Pd, L: PMe2Ph), (Pt(S3N)Cl(PMe2Ph)), and Corresponding 15N-Enriched Complexesorgano‐platinum compoundsorgano‐palladium compounds...
我們利用密度泛函理論(DFT)搭配天然鍵性論(NBO)分析法對過渡金屬羰基錯合物M(CO)42+,M(CO)3Lq[M=Ni2+, Pd2+, Pt2+;L=F-, Cl-, Br-, H2O, CN-, NH3, NMe3, PMe3, P(OMe)3, PF3]之CO 2π及碳上的孤對電子(5σ)的電子雲密度進行探討,並由E(2)值分析得知金屬回饋鍵結趨勢. 研究...
DFT analysis suggests that one of these is a non-planar triplet, while the second may be the cis-Rh(CO)(PMe 3) 2Cl isomer.doi:10.1016/S0022-328X(02)01312-8Thomas E BitterwolfW.Bruce ScallornJ.Timothy BaysCallie A WeissRinaldo Poli...
The Nujol glass matrix photolyses of Rh(CO)(PMe3)(2)Cl (1), Rh(CO)(PBu3)(2)Cl (2), Rh(CO)(2)(i-Pr2HN)Cl (3), and Rh(CO)(i-Pr2HN)(2)Cl (4), have been examined. Phototolysis of 1 (lambda(irr) > 400 nm) and 2 (350 < lambda(irr) < 400 nm) give new ...
Evaporation of the CH,Cl, in U ~ C U O yielded [Pt(S,N,H>Cl(PMe,Ph)] (la) as well formed yellow micro- crystals (81 mg, 68%) (Found: C, 21.9; H, 2.4; N, 5.8. C8Hl,ClN,PPtS2 requires C, 20.8; H, 2.4; N, 6.173. The 31P n.m.r. spectrum shows a singlet at ...
Mercury(II) halide adducts of an olefinic double betaine: [?Hg2L2X4·6HgX2?n] [X = Cl, Br; L = cis-(pMe2NC5H4N+)2C2(COO−)2]Two polymeric mercury(II) halide adducts of an olefinic double betaine, cis-(p-Me2NC5H4N+)2C2(COO−)2 (L), have been prepared and characterized ...