Solla-Gullon, V. Montiel, A. Aldaz, Errors in the use of the Koutecky- Levich plots. Electrochem. Commun. 15, 42 (2012)Vidal-Iglesias F.J., Solla-Gullon J., Montiel V., Aldaz A. Errors in the use of the Koutecky-Levich plots. Electrochem. Commun. 2012; 15 :42–45....
demonstratedthatKoutecky-Levichanalysisisapplicableandyieldstheexpe~ed plotsof/-versus 一whereIisthecurrentan d istherotationspeedbutthat thevaluesoftheelectrochemicalrateconstantsinferredarethereof足Un,notko. Thus,for >1apparentelectrocatalysismightbenaivelybutwronglyinferred whereasfor <1thededucedelectrochemical...
Koutecky-Levich plotsRelative errorA frequently employed method for the diagnosis of electrochemical mechanisms is the Koutecky-Levich (KL) method. This method is based on the extrapolation of the reciprocal of the current intensity (or density) versus the reciprocal of the square root of the ...