The kinetic behaviour of the acetic acid catalysed reaction of 2-phenyl-4,4-dimethyl-2-oxazolin-5-one ( 1) with the ethyl ester of DL-alanine ( 2) in CCl 4, to give the ethyl ester of N-(N′-benzoyl-α-amino-isobutyryl)- DL-alanine ( 3) is investigated. Within the range of ...
The kinetics of the acid-catalysed hydrolysis of some methyl 4,6-O-benzylidene-hexosidesRates of hydrolysis at 40° of the benzylidene residue in methyl 4,6-O-benzylidene- d-hexosides by 96% aqueous ethanol which was 0·03 M in hydrochloric acid, have been measured. The hexosides were ...
The kinetics of oxidation of substituted toluenes by pyridinium fluorochromate(VI) (PFC), C5H5N\\\overset+HCrO3F−, in aqueous acetic acid, in the presence of perchloric acid, have been studied. The main products are the corresponding... B Bhattacharjee,MN Bhattacharjee,M Bhattacharjee,......
Both the ionized (S) and non-ionized (SH) forms of maleimide are reactive towards the free base component of buffer solutions of trimethylamine and 1,4-diazabicyclo[2.2.2]octane. These amines have exhibited general acid-catalysed and uncatalysed nucleophilic attack at carbonyl carbon of both ...
A negligible effect of addition of mercuric acetate and potassium chloride on the reaction rate was recorded. Ionic strength (μ) of the medium exerts an insignificant effect. The main oxidation product was found to be the corresponding acid of the substrate. On the basis of the experimental ...
Edmondson DE, Newton-Vinson P (2001) The covalent FAD of monoamine oxidase: structural and functional role and mechanism of the flavinylation reaction. Antioxid Redox Signal 3(5):789–806 CAS PubMed Google Scholar Edmondson DE, Mattevi A, Binda C, Li M, Hubalek F (2004) Structure and ...
Kinetics of the uncatalysed and silver(I)-catalysed oxidation of hydrogen peroxide by [ethylenebis(biguanide)]silver(III) ion in acid perchlorate media In aqueous acid media [ethylenebis(biguanide)]silver(III) oxidises H2O2 to O2, itself being reduced to AgI and ethylenebis(biguanide): a 1 ...
Experimental designs for estimating the parameters of the Michaelis-Menten equation from progress curves of enzyme-catalyzed reactions When the progress curve for an enzyme catalysed reaction follows the integrated Michaelis-Menten equation, the maximum velocity and Michaelis constant can ... RG Duggleby...
A more robust kinetic model of base-catalysed transesterification than the conventional reaction scheme has been developed. All the relevant reactions in t... VC Eze,AN Phan,AP Harvey - 《Bioresource Technology》 被引量: 21发表: 2014年 Parametric and kinetic study of simultaneous esterification and...
A more robust model of the biodiesel reaction, allowing identification of process conditions for significantly enhanced rate and water tolerance A more robust kinetic model of base-catalysed tran AP Harvey,VC Eze,AN Phan - 《Bioresource Technology Biomass Bioenergy Biowastes Conversion Technologies Biotra...