Inspired by biosynthesis, we have investigated the natural product synthesis utilizing electrochemical reactions as the key step, in which anodic oxidation of phenol compounds afford the important frameworks such as diaryl ether, spirodienone, and spiroisoxazoline.doi:10.1002/tcr.202100032...
These key compounds are used to compare the results from earlier studies of model compounds such as, e.g., glucose or cellulose, with biomass degradation in order to identify chemical reaction pathways. Key compounds identified are phenols (phenol and cresols), furfurals, acids (acetic acid, ...
Tishchenko O, Truhlar DG, Ceulemans A, Nguyen MT (2008) A unified perspective on the hydrogen atom transfer and proton-coupled electron transfer mechanisms in terms of topographic features of the ground and excited potential energy surfaces as exemplified by the reaction between phenol and radicals...
In addition, phenolic hydroxyl groups on electron-poor aromatic systems (i.e., carrying additional nitro substituents) should be avoided due to undesired side reactions (i.e., Ugi-Smiles where the acidic phenol acts as acid component). Since the molecular keys are designed for tandem mass ...
Hopefully you can see that the aromaticity of phenol (with its resonance energy of >20 kcal/mol) greatly favors the enol form here. The keto tautomer can’t be detected in solution!11. Revisiting An “Un-Ketone-Like” Reaction With Br2After all we’ve explored, I think we’re ready ...
DyP2 has demonstrated high manganese peroxidase activity and lignin depolymerization ability, with broad spectrum of substrate specificity, demonstrating peroxidase activity toward phenol, azo dyes and anthraquinone dyes. Laccase Laccase is a multicopper oxidase that is widely used in the biological industry...
DyP2 has demonstrated high manganese peroxidase activity and lignin depolymerization ability, with broad spectrum of substrate specificity, demonstrating peroxidase activity toward phenol, azo dyes and anthraquinone dyes. Laccase Laccase is a multicopper oxidase that is widely used in the biological industry...
N2A cells transfected with PIEZOmScarlet constructs were prepared as described above and imaged in phenol-red free medium. Time-lapse recordings were preprocessed in Fiji (v2.3.0/1.53f) before track analysis, with a background subtraction and a bleach correction (Histrogram matching). PIEZO...
ER-phagy was induced with media starvation using EBSS with calcium, magnesium, and phenol red (Invitrogen e10043). For EATR and CCER assays, cells were plated 48 hours prior to EBSS treatment. EATR expression is induced using 4 μg/ml doxycycline 24hr prior to starvation. Unless otherwise ...
RNA was purified by phenol: chloroform extraction and precipitated with ethanol. Its purity and concentration were assessed using a spectrophotometer (NanoDropTM, ThermoFisher). cDNA was obtained with the High-Capacity cDNA Reverse Transcription Kit (ThermoFisher), following the provider's instructions....