kamlet-taft参数 Kamlet-Taft参数是一组描述分子溶剂作用的物理化学指标。它由Kamlet和Taft于1976年开发,旨在量化分子溶剂对水合作用的影响。这个参数通常用于描述有机分子在溶液中的化学行为,如离子溶解度、配位化学和反应机理。 Kamlet-Taft参数由三个度量组成,即极性(π)、氢键接受性(α)和氢键给性(β)。其中,π...
对于该方程中E表示absorption/fluorescence energy ,E0表示the value independent of the solvent ,s、a...
Phys., 2016, 18, 13153--13157 | 13153Cite this:Phys.Chem.Chem.Phys.,2016, 18, 13153Determination of Kamlet–Taft parameters forselected solvate ionic liquids†Daniel J. Eyckens, ab Baris Demir, a Tif f any R. Walsh, a Tom Welton c andLuke C. Henderson* abThe normalised polarity E...
Kamlet–Taftparameters(a,b,andp*),andcomparedtheseto theircorrespondingvaluesfortheparentglymesolvent(G3and G4,respectively),and[Bmim][TFSI],toprovidecontextand methodvalidation. The solvate ILs which are the focus of this work (Scheme 1) are reminiscent of concentrated solutions of lithium per- ...
哪位虫友知道如何测量一种溶剂的Kamlet-Taft溶剂参数(π,α,β),谢谢!