Kamlet–Taft parameterssolvate ionic liquidp>The Kamlet–Taft solvent parameters of solvate ionic liquids (SILs) prepared from lithium salts with glyme and glycol ligands are determined. The dipolarity/polarisibilities (π*) are high, similar to those found in conventional ionic liquids. The H-...
Kamlet–Taft solvent parameters,π*, of high pressure and supercritical water were determined from 16–420 °C based on solvatochromic measurements of 4-nitroanisole. For the measurements, an optical cell that could be used at high temperatures and pressures was developed with the specification of ...
A correlation matrix between other known solvent parameters and the measured Kamlet–Taft values revealed only one correlation, suggesting that the three measured Kamlet–Taft parameters for the glycol ethers are independent solvent descriptors. Last, trends in the measured Kamlet–Taft values were ...
Therefore, we have characterisedG3TFSI and G4TFSI in terms of normalised polarity (E NT ),Kamlet–Taft parameters (a, b, and p*), and compared these totheir corresponding values for the parent glyme solvent (G3 andG4, respectively), and [Bmim][TFSI], to provide context andmethod ...
a TomWelton c and LukeC.Henderson* ab ThenormalisedpolarityE N T andKamlet–Taftparametersofrecently describedsolvateionicliquids,composedoflithiumbis(trifluoro- methyl)sulfonimide(LiTFSI)intri-(G3TFSI)ortetraglyme(G4TFSI) havebeendeterminedandcomparedtotheparentglyme(G3and G4).Weshowthatthesesolvate...
We used Kamlet–Taft parameters to quantify the solvent polarity of the ionic liquids and found that the anion basicity described by the parameterβ... A Brandt,JP Hallett,DJ Leak,... - 《Green Chemistry》 被引量: 245发表: 2010年 Role of Solvent Parameters in the Regeneration of Cellulose...
ChemInform Abstract: Application of the Kamlet and Taft Model in Solvent Extraction Chemistry of Metalsanalytical chemistryreviewseparation and purification methodschromatographyChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading ...
Kamlet-Taft parameterssolvate ionic liquidThe Kamlet-Taft solvent parameters of solvate ionic liquids (SILs) prepared from lithium salts with glyme and glycol ligands are determined. The dipolarity/polarisibilities (pi*) are high, similar to those found in conventional ionic liquids. The H-bond ...
Kamlet Taft parameterssolvent characteristicshazardous indexhazardous dipolar aprotic solventsolvent-pair mixtureIn chemical synthesis, the uses of solvents are inevitable, and it has been a practice since the inception of the process. With time it gets into the notice that most of the essential ...
A correlation matrix between other known solvent parameters and the measured Kamlet–Taft values revealed only one correlation, suggesting that the three measured Kamlet–Taft parameters for the glycol ethers are independent solvent descriptors. Last, trends in the measured Kamlet–Taft values were ...