Thermoanalytical study of linkage isomerism in coordination compounds part III: A DSC study on the counterion effect on the solid state isomerization of nitro and nitrito linkage isomers of pentaammiecobalt(III) complexes. Thermochim. Acta 2014, 575, 114-121. [CrossRef]...
Compounds 1-2, 3-4, and 5-6 are three pairs of linkage isomers since they present the same formula and chain structure and they only differ in the connectivity of the polynitrile ligand bridging the metal ions in the chain: through a N and an O atom (1κN:2κO-isomer) or through...
All products were found to be coordination polymers. The crystal structures of {[Cd(L1)(NO3)2]·CH2Cl2}∞ (1a), {[Cd(L1)(NO3)2]·4/3CH3CN}∞ (1b), {[Cd2(L2)(NO3)4]·2CH3CN}∞ (2·2CH3CN), and {[Cd2(L2)Cl4]·2CH2Cl2}∞ (3·2CH2Cl2) were determined. Compounds 1a ...
二、化学结构异构现象,大致分为五类:Ionization isomerism,Hydrate isomerism,Linkage isomerism,Coordination isomerism,Polymerization isomerism.1.Ionization isomerism(1) Two coordination compounds which differ in the distribution of io
Coordination geometry isomerism induced by N-H… C1,C-H…Cl,C-H… N,C-H…π and π…π supramolecular interactions in mercury(Ⅱ) complexes with tripyridylimidazole chelating ligands[J].Inorganica Chimica Acta 2008,361.Campos-Gaxiola J J, Hopfl H, Parra-Hake M. Coordination geometry ...
声明:本网站尊重并保护知识产权，根据《信息网络传播权保护条例》，如果我们转载的作品侵犯了您的权利,请...
二、化学结构异构现象,大致分为五类:Ionization isomerism,Hydrate isomerism,Linkage isomerism,Coordination isomerism,Polymerization isomerism.1.Ionization isomerism(1) Two coordination compounds which differ in the distribution of io
Compounds 1 and 4 show a very similar thermal behaviour, the two water molecules being lost in the temperature range 25–150 and 160–320 °C, respectively. Temperature dependent X-ray powder diffractometry (TDXD) has been performed on compound 1 in order to follow the structural ...
compoundsMagneticpropertiesIsomerismMagneticexchangeNickelthiocyanateReaction of Ni(NCS)2 with different co‐ligands based on pyridine derivatives substituted in 4‐position leads to the formation of 1D coordination polymers with the composition [Ni(NCS)2(co‐ligand)2]n, in which the metal cations are...
Experimental methods for distinguishing the geometrical isomerism provided in the chapter are an important supplement to the study. Similarly, after the discussion on optical isomerism, a note on racemization will also provide added information on the topic. Attempts have been made to explain each ...