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Triazole 1 was treated with n-BuLi followed by exposure to propionitrile (2) and acidic quench to give racemic alcohol 3 in 65% yield. Next, resolution of this racemic alcohol was facilitated through the use of camphor derivative 4 to provide alcohol 5 in 38% yield and 99% ee. Nitrile ...
Can be selectively removed in the presence of a t-BuPh2Si-protected alcohol. Used in a preparatrion of isoxazoline N-oxides from α-bromonitroalkanes. Trimethylsilyl ethers are too susceptible to solvolysis for them to have any utility as protecting groups. The tert-butyldimethylsilyloxy group ...
Each gram of PLIAGLIS contains lidocaine 70 mg and tetracaine 70 mg in a 1:1 eutectic mixture and it also contains the following inactive ingredients: anhydrous dibasic calcium phosphate, methylparaben, polyvinyl alcohol, propylparaben, purified water, sorbitan monopalmitate, and white petrolatum. 12...
DButanal is formed . Submit Acetone forms bisulphite compound when heated with sodium bisulphate whears di-tertiary butyl ketone fails to do so. Explain. View Solution A mixture containing primary, secondary and tertiary amine is treated with diethyl oxalate. Choose the correct statement ...
Precipitates is formed by adding an alcohol selecting from methanol, ethanol, isopropyl alcohol, tert-butyl alcohol and n-butyl alcohol into a dimethyl sulfoxide solution; salt formation; hypotensive agent for treating eye hypertension; stability
The evaporated crude extract suspended in H2O was extracted by petroleum ether, ethyl acetate and n-butyl alcohol successively. Briefly, the ethyl acetate extract was sequentially partitioned with a gradient of MeOH-H2O (3:7 to 1:0), CH2Cl2-MeOH (200:1 to 0:1), MeOH (100%) and a ...
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a) Diethyl ether b) Ethanol c) Water d) Acetaldehyde What alcohol might the given alkene have been made from? Which of the following is a primary alcohol? A)CH3CH2OH B)(CH3)2CHOH C)(CH3)3COH D)(CH3)2CHCH(CH3)OH E)CH3OCH3 What is the bonding functional group for ethanol...