In the ionic compound [(UO2)2Cl2(L1)3][(UO2Cl3)2(L1)] (10), independent binuclear anions traverse the cells of the underlying cationic hcb network. The compound [(UO2)5(L1)7(tdc)(H2O)][(UO2)2(tdc)3]4CH3CN12H2O (11) features a fascinating self-sorting characteristic driven by...
In all cases, both models report open shell interactions as expected of covalent bonds; however, the differences in magnitude can be attributed to the first two bonds being hydrogen bond donors, while the third is a hydrogen bond acceptor. Similar trends can also be seen in the analogous ...