Iron-catalyzed C–H bond activation followed by C–C bond formation has received much attention in recent years, motivated by the environmental and economical merits of iron, as well as the scientific challenge in controlling and understanding the reactivity of iron species. This review describes ...
1)iron-catalyzed铁催化 1.In recent years, copper, iron-catalyzed Ullmann coupling reactions have attracted much attention, and some useful domino processes have been developed to construct nitrogen heterocycles via Cu-catalyzed Ullmann-type reactions.近年来,铜、铁催化的Ullmann偶联反应越来越受到研究者的...
iron electron-shuttle catalysis, leading to the observed high chemoselectivity. Introduction Olefins serve as a sought-after class of feedstocks for chemical synthesis by virtue of their wide existence, availability as well as versatility1,2,3. The intermolecular difunctionalization of olefins by introduc...
The catalysis by iron of the formation of reactive oxygen species in biological systems has been well documented. In this present study, we have investigated the hypothesis that iron-catalyzed formation of hydroxyl radical (.OH) from superoxide anion radical (O-.2) and H2O2 requires the ...
Jakob Norinder,Arimasa Matsumoto,Naohiko Yoshikai,Eiichi Nakamura.Iron-Catalyzed Direct Arylation through Directed C?H Bond Activation. Journal of the American Chemical Society . 2008Norinder, J,Matsumoto, A,Yoshikai, N,Nakamura, E.Iron-Catalyzed Direct Arylation through Directed C-H Bond Activation....
1) iron-catalyzed 铁催化1. In recent years, copper, iron-catalyzed Ullmann coupling reactions have attracted much attention, and some useful domino processes have been developed to construct nitrogen heterocycles via Cu-catalyzed Ullmann-type reactions. 近年来,铜、铁催化的Ullmann偶联反应越来越受到...
来自 掌桥科研 喜欢 0 阅读量: 6 摘要: An efficient and convenient iron-catalyzedprotocol has been developedfor the synthesis of substituted pyrrolo[1,2--acetyl oximes through N–O bond cleavage and intramoleculardirected C–H arylation reactions in acetic acid. DOI: 10.1021/acs.joc.5b00915 ...
An efficient one-pot procedure for the synthesis of multisubstituted xanthone derivatives using Fe-catalyzed reactions of 2-aryloxybenzaldehydes followed by DDQ(2,3-dichloro-5,6-dicyano-1,4-benzoquinone) oxidation has been developed.This method offers a convenient high-yield route to xanthones from...
ChemInform Abstract: Iron-Catalyzed Suzuki—Miyaura Coupling Reaction of Unactivated Alkyl Halides with Lithium Alkynylborates. A Suzuki—Miyaura coupling reaction between unactivated alkyl halides and lithium alkynylborates is performed using an iron—bisphosphine catalyst. Naohisa,Nakagawa,Takuji,... - ...
Iron-Catalyzed Cα-H Oxidation of Tertiary, Aliphatic Amines to Amides under Mild Conditions.doi:10.1002/anie.201507738C?HfunctionalizationironcatalysismetabolitesynthesisoxidationreactionmechanismDe novo syntheses of amides often generate stoichiometric amounts of waste. Thus, recent progress in the field...