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On the other hand, the [O(1)–CCC–N(1)] plane makes dihedral angles of 34.8(2)◦ and 14.8(5)◦ with that of its 4-fluorophenyl and substituted Cp ring substituents in 3 and 5, respectively. Like in the free proligand 2, the NO2 group is almost coplanar (4.1(6)◦) with...