The title compound, [Fe(C11H18N3O2)(H2O)]Cl, is a mononuclear iron(II) complex, consisting of one coordination cation and one uncoordinated Cl− anion. The central metal has distorted square-pyramidal geometry. Weak intermolecular hydrogen bonds link the molecules to form two-...
The quaternary complex formed by the tris(2,2'-bipyridine)iron(II) cation and the tetraiodocadmate(II) anion can be readily extracted into benzyl alcohol. The extracted complex shows a well-defined reduction wave in the ternary electrolyte-solvent mixture, composed of benzyl alcohol, an aqueous...
Ferroptosis is a cellular process dependent upon excess iron, reactive oxygen species (ROS), and phospholipids (PLs) that contain polyunsaturated fatty acid chains (PUFAs).9,10Ferroptosis can be initiated by two primary pathways, namely the exogenous (transporter-dependent) pathway and the endogenous...
Conversely, when the iron complex had a negative charge (Fe−Cit), the cell was assembled in a cation-anion-cation exchange membrane (CAC). A peristaltic pump (Ismatec Reglo ICC, Cole-Palmer) was used to supply water to the FCDI cell, and a pump (MasterFlex Easyload II Dual Channel)...
The results indicate the existence of an iron/diorganyl diselenide complex, which forms both a cation and an anion of organoselenyl. In an attempt to prove the synthetic application of 3‐(organoselanyl)‐1,2‐dihydroquinolines prepared, we evaluated their use as substrates in the transition ...
(II) complexIM2, followed by a metal-to-ligand single electron transfer along with the cleavage of O − N bond, which was eventually converted to an Fe(III)-aminyl radical intermediateIM4. Spin population analysis reveals there is significant spin density at the nitrogen center (−...
Participation of silicon in cation-anion balance as a possible mechanism for aluminum and iron tolerance in some gramineae. J Plant Nutr 16: 547-553.Wallace, A. 1992: Participation of silicon in cation-anion balance as a possible mechanism for aluminum and iron tolerance in some Gramineae. J....
A triple-electrolyte-designed flow cell was assembled with a combination of cation (Nafion 112 or Nafion 211) and anion (FAA-3 or A901) exchange membranes. The neutral electrolyte was used as the middle electrolyte to control the pH of the anolyte and catholyte. Here the middle electrolyte ...
The kinase CPDK1 was used as a control as it has been investigated by CETSA33 and has the ability to bind to the divalent cation Ca2+ but is not expected to bind to iron. As expected, incubation with FAC did not affect the solubility of CDPK1, which showed 50% protein solubility at...
ChemInform Abstract: LOW㏕EMPERATURE MAGNETISM OF LOW㏒PIN IRON(II) CATION HIGH㏒PIN IRON(III) ANION COMPLEXES. SUPPORTING EVIDENCE FOR THE TRUE NATURE OF SO〤ALLED ′SPIN㏕RIPLET IRON(II)′ COMPOUNDSdoi:10.1002/chin.198235270organo﹊ron compounds...