The charge distribution in both the phosphonium cation and the phosphate anion is discussed in detail. We can conclude that the P 2pbinding energy for the cationic phosphorus centre is lower than that of the anion-based phosphorus centre. The electronic environment of the anionic fluorine, ...
The compound contains the polyatomic ion PO43−, consisting of one phosphorus atom and four oxygen atoms, and having an overall charge of 3−. This formula indicates that there are three Ca2+ ions (total six positive charges) for every two PO43− groups (total six negative charges...
Besides the common anion structures mentioned above, several relevant studies of SICPEs based on other anionic groups (i.e., using phosphorus [121] and aluminum [85,122,123] as center atoms) have been explored. For example, the dynamic single ion conducting network (DSN, Fig. 4g) was rece...
s suggestions between 1827 and 1858 by showing that similar relationships extended further than thetriadsof elements,fluorinebeing added to the halogens andmagnesiumto the alkaline-earth metals, whileoxygen,sulfur,selenium, andtelluriumwere classed as one family andnitrogen,phosphorus,arsenic,antimony, ...
The chlorides were characterized as ion pairs and contrasted to the previous interpretation as charge-transfer complexes between carbene and dichlorine. Furthermore, the two precursors are used for the synthesis of a series of new carbene complexes of phosphorus(v) fluorides substituted with ...
Because of the ease of introducing various type of side chains, polyphosphazenes are particularly versatile among the inorganic polymers for polymer electrolyte application. Linear polyphosphazene is the macromolecule with inorganic backbone formed by alternating phosphorus and nitrogen atoms in the skeleton ...
(CB) imparts the photoelectrons of CN sufficient thermodynamic energy for the reduction of CO2. Nevertheless, its photocatalytic performance still suffers from fast charge carrier recombination as well as the lack of catalytic sites. Therefore, the photocatalyst design of CN-based photocatalysts is ...
Maier, J. Space charge regions in solid two-phase systems and their conduction contribution. III. Defect chemistry and ionic-conductivity in thin-films. Solid State Ion. 23, 59–67 (1987). CAS Google Scholar Lacivita, V. et al. Resolving the amorphous structure of lithium phosphorus oxynit...
for example, concentrations the abundance of Haloquadratum and Halorubrum- of nitrogen, phosphorus and dissolved organic related strains in Lake Tyrrell (Emerson et al., 2013) material, or biological predation stresses imposed as well as other extreme hypersaline environments by viruses and/or picoeukar...
An ionic liquid including a phosphazene compound that has a plurality of phosphorus-nitrogen units and at least one pendant group bonded to each phosphorus atom of the plurality of