Co_(1-δ)OA new experiment has been designed on the basis of the polarization in an ion-blocking electrode condition, which allows one to simultaneously determine the ionic charge-of-transport ( ja:math ) and chemical diffusivity ( ja:math ) of a mixed conductor compound, A 1 δ O, ...
Method for the ab initio calculation of intermolecular potentials of ionic clusters: Test on Rg–CO[sup +], Rg=He, Ne, Ar. The interaction energy of a cationic complex A-B[sup +] can be computed as the sum of the interaction energy of the neutral complex A-B and the geometry de.....
Ruleofthumb:Ionic(Metal-Nonmetal)Covalent(Nonmetal–Nonmetal)Metallic(Metal–Metal)Tounderstandwhythisruleofthumbgenerallyworksour,weneedtorevisit theconceptofelectronegativity.Electronegativity TheelectronegativityscalewasdevelopedbyLinusPauling.Electronegativity:thepowerofanatominamoleculetoattractelectronstoitself.6 Linu...
Therefore, the critical aggregation concentrations (CACs) of the [Ch][FA] are measured by the indication of the ACQ fluorescence. Molecular dynamics simulation reveals the dynamic co-aggregation of choline oleate ([Ch][Ole]) in water. The enhanced oral bioavailability of [Ch][Ole]-based ICAs ...
On the other hand, the AlF(4) and AlCl(4) superhalogens were found to be incapable of reacting with molecules whose ionization potentials (IP) exceed 13 eV (e.g., CO(2), CH(4)). Finally, it is demonstrated that the competition between the electron binding energy of the superhalogen...
A2–αA′αBO4-type oxides as cathode materials for IT-SOFCs (A = Pr, Sm; A′ = Sr; B = Fe, Co). Mater. Lett. 60, 1174–1178 (2006). CAS Google Scholar Tarasova, N. A. & Animitsa, I. E. Effect of anion doping on mobility of ionic charge carriers in solid solutions ...
we postulate a rate determining step in the reaction of CO2 and H2O: $${\mathrm{EMIM-BF}}_4 + {\mathrm{CO}}_2 + x{\mathrm{H}}_2{\mathrm{O}} \to \left[ {{\mathrm{EMIM}}^\ast{\mathrm{-CO}}_2} \right] \\ + \left[ {{\mathrm{BF}}_{4-x}\left( {{\mathrm{OH}}}...
The results indicate that CO adsorbed on the Pt electrode has a Stark shift of 3035 cm-1/V in the ionic liquid. The potential of zero charge (PZC) of the ionic liquidPt system is approximately 500 mV (vs Ag wire), with a capacitance of 0.12 F/m2. Further, polarization-dependent SFG...
International Journal of Mass SpectrometryBalteanu, I.; Achatz, U.; Balaj, O. P.; Fox, B. S.; Beyer, M. K.; Bondybey, V. E. The Effect of Charge upon CO-Adsorption by Ionic Group 5 and Group 9 Transition Metal Clusters. Int. J. Mass Spectrom. 2003, 229, 61-65....
Synthesis of co-modified g-C3N4nanosheets by IL and Co single atoms The IL/Co-bCN photocatalyst with dual-cocatalysts was synthesized as the procedures illustrated in Fig.1. Using melamine and cyanuric acid as the raw material, pristine CN was fabricated by the H-bonding-induced self-assembling...