The hydrogen bond accepting parameter 𝛽β is primarily dominated by the anion and affects the stability of proteins significantly [121]. 𝛽β values higher than 0.8 are known to deactivate protease, which has been rationalized by the fact that the ionic liquid anions interfere with the ...
Structural effects on thermodynamic behavior and hydrogen bond interactions of water–ionic liquid systems. Chem. Eng. Sci. 2021, 230, 116186. [Google Scholar] [CrossRef] Freire, M.G.; Neves, C.M.S.S.; Marrucho, I.M.; Canongia Lopes, J.N.; Rebelo, L.P.N.; Coutinho, J.A.P....
[88] found that for rare earth elements adsorbed on the surface of clay minerals in the form of chemical bond, the interaction between sodium dodecyl sulfate and rare earth elements greatly reduces the RE-O chemical bond strength between rare earth and O atoms on the mineral surface, which ...
However, there are at least two open questions which should be studied in the future: — are the correction factors Fim designed in this work for [Cnmim][Anion] series common for the pyridinium, pyrrolidinium, ammonium, amd phosphonium, etc. based ionic liquids connected to the same anion?
To circumvent the thermodynamic limitation of the synthesis of oxazolidinones starting from 2-aminoethanols and CO2 and realize incorporation CO2 under atmospheric pressure, a protic ionic liquid-facilitated three-component reaction of propargyl alcohols
This research explores the potential of ionic liquids (ILs) in restoring paper artifacts, particularly an aged book sample. Three distinct ILs—1-ethyl-3-propylimidazolium bis(trifluoromethylsulfonyl)imide, 1-methyl-3-pentylimidazolium bis(trifluoromethy
The presence of Ba was found to decrease the Fe2O3 to Fe3O4 reduction onset at approximately 168 °C, indicating a strong promoting effect that could be ascribed to the activation of either the Fe-O bond (toward iron oxide reduction) or C-O bond (toward the formation of CO2 from ...
Another feature explored is the resistance of the coatings, in terms of composition and surface microstructure, toward seawater. This can simply leach the IL away, since the bond between the IL and the binder may exhibit a reversible nature. The seawater can also have an effect on the microstr...
The temperature was kept constant using the Parrinello thermostat [46], the bond lengths were constrained using Lincs algorithm [47] and the electrostatics were taken into account using a cut-off of 0.8 nm and 1.1 nm for short-range and long-range electrostatics. All the simulations, carried ...