The physical meaning of this parameter is related to the dynamics of the reactions. The profiles of the distance and free energy dependences of photoinduced ET rates are closely reproduced. The occurrence of distance-dependent non-adiabatic factors in intermolecular sigma*-d ETs is rationalized....
Alright. So here, we have this structure and it's showing us this squiggly squiggly line for OH, meaning that it can orient itself up or down. Now, if we orient this, let's say we're going to orient it down, we're going to draw this bicyclic compound. Now, t...
This trend is also true in the case of 2a-H and 2g-H, meaning that extending p- conjugated plane along the long axis of pentalene derivatives mainly raised the HOMO levels, with LUMO levels almost Table 2 | Summary of the photophysical and electrochemical properties of compounds 2a, 2f and...
There is no signature of a singlet transition for the other half of the dimer in our sensitized triplet spectra, meaning any such transition must be shifted to below 500 nm. As for the third assumption, we note that the constant GSB we observe in that spectral region during SEF requires ...
Upon retraction, the tip remains intact meaning that this instability is reversible. Similarly, the Ag-terminated Si tip, Fig. 4(e), shows unstable behaviour above adatom sites as the Ag atom jumps to the surface. It does not, however, remain there remain there upon retraction, i.e. this...
The physical meaning which should be imparted to the Urey-Bradley potential, in particular, follows from the analysis presented.doi:10.1007/BF01392197I. M. GinzburgN. D. SokolovKluwer Academic PublishersTheoretical & Experimental Chemistry
In this contribution, a convenient expression of the macro-cyclic index (m-CI) was presented and deduced as the ratio of NA/NB of HyperMacs to that of their completely intramolecular cyclized analogues. The physical meaning of m-CI is the similarity of HyperMacs to their completely cyclized ...
The spectral function is calculated and its physical meaning is discussed. The differential conductance/bias voltage and the tunnel current/bias voltage correlations are considered. It is shown that these correlations depend strongly on the value of the overvoltage and the extent of Debye screening ...
Mp/Mp,O for S6 (0.72) was smaller than that for S7 (0.87), meaning that S6 was more compact than S7 in comparison with their corresponding precursors. This is because P6-O has fully mobile pendant olefins in high concentration that are efficiently crosslinked into S6. Selective single-chain...
The term "nondiffusing" used herein has the meaning commonly applied to the term in photography and denotes materials which for all practical purposes do not migrate or wander through organic colloid layers in an alkaline medium, such as gelatin, in the photographic elements of the invention. The...