The inductive effect affects the stability as well as acidity or basicity of a chemical species. Electronegative atoms draw electrons toward themselves, which can stabilize a conjugate base. Groups that have -I effect on a molecule decrease its electron density, making the molecule electron deficient...
Further analysis of the literature showed anomalous charge densities for haloalkanes with 13 C NMR spectroscopy and gas phase acidity of polyatomic acids. In summary, these independent results show that the induction effect does not explain p K a trends across the haloacetic acids.Edwin C. ...
inductive[in'dʌktiv] [网页划词已开启] 英汉解释 adj. [逻]归纳的;[电]感应的;诱导的 同义词 a.inducive 反义词 a.deductive 参考例句 1. Luna: Was itinductive? 那个是感应的么? 2. This paper expounds the negativeinductiveeffect of alkyl and explains the order of acidity of some substances...
What would be the effect on the [{Image src='img88859981090891876725.jpg' alt='' caption=''}].reaction shown above if chlorobenzene was substituted for the benzyl chloride? What would be the effect on What is the difference between acetylmorphine and aspirin? How does biochemistry differ...
Explain the terms Inductive and Electromeric effects. Which electron displacement effect explains the following correct orders of acidity of the carboxylic ac
External fixators bring the advantages of exerting a minimal effect on the blood supply of fracture fragments and little soft tissue injury, and the wound is limited to the nail tract, which reduces the risks of infection [19]. Moreover, the external fixator can reduce stress shielding of ...
Also, the classical inductive effect accounts for the acidity of dissolved alkanols and hence provides a straightforward explanation for the well known acidity inversion in alkanols from the gas phase to a solution. The applicability of the derived I and P values for the alkyl groups to the ...
aciditybasicityThe classical concept of inductive effect based originally on dissociation constants in water was revisited on isolated molecules in the gas phase. It then has a strict thermodynamic meaning of ΔHo(g) of an isodesmic reaction and can be calculated separately in the neutral molecules...
aciditybasicityThe classical concept of inductive effect based originally on dissociation constants in water was revisited on isolated molecules in the gas phase. It then has a strict thermodynamic meaning of ΔHo(g) of an isodesmic reaction and can be calculated separately in the neutral molecules ...