A multi-step scheme for the electrochemical reduction of (I ag ) is suggested to explain the various experimental results obtained.doi:10.1016/S0022-0728(72)80454-6RomanoAndruzzi,MarioEmilioCardinali,ItaloCarelli,AntonioTrazzaElsevier B.V.Journal of Electroanalytical Chemistry...
The modified indolenines can be efficiently converted to C-2-sides chain alkylated indoles by reduction with lithium-aluminum hydride or zinc.doi:10.1016/S0040-4039(00)86960-9Susan F. ViceEdward A. GrossRichard W. FriesenGary I. Dmitrienko...
ChemInform Abstract: A New Method for Regiospecific Deuteriation and Reduction of 5,10,15, 20㏕etraphenylporphyrins: Nucleophilic Reaction of Borohydride I... ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To...
The electrochemical reduction product is 1-hydroxy-2-phenyl-3-arylaminoindole corresponding to the first wave (A) and 2-phenyl-3-arylaminoindole corresponding to the second wave (D). A multi-step scheme for the electrochemical reduction of (I a-f) is suggested to explain most of the ...
ChemInform Abstract: ELECTROCHEMICAL BEHAVIOR OF 3-IMINOINDOLENINE DERIVATIVES IN DIMETHYLFORMAMIDE. PART IV. REDUCTION OF 2-PHENYL-3-((1-ALKYL(O PHENYL)-2-PHENYL-3-INDOLYL)IMINO)-3H-INDOLES AND THEIR MONO N-OXIDESdoi:10.1002/chin.197619093...
The reaction of the >P-O− reagent with 2-phenyl-3-phenyliminoindolenine N-oxide 1 gave reduction product, namely 2-phenyl-3-phenylimino-3H-indole 2. Dialkyl phosphites undergo nucleophilic addition into endo C[dbnd]N double bond of the 2-phenyl-3-phenyl-imino-3H-indole 2 to furnish ...
The reaction of the >P-O reagent with 2-phenyl-3-phenyliminoindolenine N-oxide 1 gave reduction product, namely 2-phenyl-3-phenylimino-3H-indole 2. Dialkyl phosphites undergo nucleophilic addition into endo CN double bond of the 2-phenyl-3-phenyl-imino-3H-indole 2 to furnish dialkyl 2-...
A sequence of reduction of nitroarene to nitrosoarene followed by 6蟺-electron-5-atom electrocyclization and a 1,2-alkyl shift of the resulting nitrone intermediate was proposed to account for the reaction outcome. A subsequent total synthesis of (+)-condyfoline not only illustrates the ...
Reaction with (2-(2-Nitrophenylsulfenyl)-S-methyl-3-bromoindolenine) BNPS-skatole and subsequent reduction of the 4 partially oxidized methionine residues produced a derivative of nuclease with modification only of residue 140, a single tryptophan. BNPS-skatole is poorly soluble in water. The stab...
The electrochemical reduction product corresponding to wave (A) is 1-hydroxy-2-phenyl-3-(2′-pyridyl) aminoindole (V) for compound (III) and 1-hydroxy-2-phenyl-3-(1′-oxide-4′-pyridyl) aminoindole(VI) for compound (IV). Compound (V) and 2-phenyl-3-(2′-pyridyl)aminoindole are ...