MOF-199 and Ni-BTC: Synthesis, Physicochemical Properties, and Catalytic Activity in Oxidation of 5-Hydroxymethylfurfuraldoi:10.9767/bcrec.20060Platform chemical 2,5-furandicarboxylic acid (FDCA) has potential applications to replace petroleum-based chemicals. Metal Organic Framework (MOF) c...
In this context microporous 3D Tb(BTC)(H2O).(DMF)1.1 MOF was incorporated into pristine Matrimid® with loadings of 10, 20 and 30 weight percentages. SEM micrographs indicated proper distribution of filler in the Matrimid and no interfacial voids were observed. Gas permeation studies evidenced ...
Llewellyn. Understanding CO2 Adsorption in CuBTC MOF: Comparing Combined DFT-ab Initio Calculations with Microcalorimetry Experiments[J].The journal of physical chemistry, C. Nanomaterials and interfaces 2011,36(36).Grajciar, L.; Wiersum, A. D.; Llewellyn, P. L.; Chang, J.-S.; Nachtigall,...
Emam HE, Abdelhameed RM (2007) In-situ modification of natural fabrics by Cu-BTC MOF for effective release of insect repellent (N, N-diethyl-3-methylbenzamide). J Porous Mater 24:1175-1185. https://doi.org/10.1007/ s10934-016-0357-yH.E. Emam, R.M. Abdelhameed, In-situ modification...
This study discusses the determination of thyroxine hormone in blood serum samples by a novel MOF composite electrode. The used MOF was Zn(BTC)-(MOF) which was constructed from 1,3,5-benzenetricarboxylic acid ligand (BTC) and zinc ions in DMF solvent. Using cysteine as the linker, the MOF...
To enhance the resistance of a metal-organic frameworks(MOF) to a change in the medium pH composite materials are synthesized from Cu-BTC (MOF-199) and activated carbons of various brands (AR-V, AGN-2, ART-1, BAU-A, MeKS). It is shown that the highest stab...
The presence of Pd also increases the irregularity of Zr-BTC morphology and contains an average particle size up to 16.58±6.4 nm according to SEM and TEM analysis. Modification with Pd lead to a decrease in surface area, pore volume, and diameter of Zr-BTC up to 1095 m2/g, 0.15 cc/g...
In this study, we successfully prepare Cu3(BTC)2 (commonly known as HKUST-1 or MOF-199) in aqueous media as a green method. The morphology and crystallinity of the prepared sample were studied by XRD, FT-IR, SEM, BET, and TGA. The effects of loss of uncoordinated and coordinated ...
In situ preparation of palladium nanoclusters in cerium metal-organic frameworks Ce-MOF-808, Ce-UiO-66 and Ce-BTC as nanoreactors for room temperature Suzuki cross-coupling reactionMonodisperse palladium nanoclustersCe-MOFsIn situ preparationCore-shell catalysts...
An Insight on the Electrocatalytic Mechanistic Study of Pristine Ni MOF (BTC) in Alkaline Medium for Enhanced OER and UORelectrocatalysisenergy conversionmetal-organic frameworksurea oxidationwater splittingThe strategy of compatibly integrating cost-effective HER- and OER-active materials in a well-...