In the organic compound overset1CH2=overset2CH-overset3CH2-overset4CH2-overset5CH=overset6CH2 , the pair of hybridised orbitals involved in the formation of C
Dimethyloxosulfonium Methylide ((CH3)2SOCH2) and Dimethylsulfonium Methylide ((CH3)2SCH 2). Formation and Application to Organic Synthesis. J. Am. Chem. Soc. 1965, 87, 1353– 1364, DOI: 10.1021/ja01084a034 ACS Full Text , [CAS], Google Scholar...
The homopolymer, [Zn(BunPhPO2)2]n, has been studied as a model system with a disordered positioning of the n-butylphenylphosphinate groups along the molecular chains. This compound exhibits polymorphism and its γ-form is isomorphous with that of [Zn(Ph2PO2)2]n.The zinc(II) mixed-ligand...
An agostic interaction in a RuCH sub 2 CH sub 2 Zr mo... Szalda,D.J.Complexes containing a C2 bridge between an electron-rich metal and an electron-deficient metal.An agostic interaction in a RuCH2CH2Zr moiety... Bullock,R.M,Lemke,... - Journal of the American Chemical Society; (...
A 3D metal halide framework in the organic-inorganic compound (H3N (CH1)SS (CH2)NH3)Pb5I16. Louvain Nicolas,Mercier Nicolas. Solid State Sciences . 2008Louvain Nicolas,Mercier Nicolas.A 3D metal halide framework in the organic-inorganic compound (H3N (CH1)SS (CH2)NH3)Pb5I16. Solid State...
To shed further light on the formation of compound 11, the mechanism for the formation of this remarkable species was subject to a computational investigation. Calculations based on density functional theory (DFT) employing the model complex 6′ suggest that the mechanism proceeds through two sequenti...
The halogen bonding complexes H2O ⋯ M (M = F2, ClF, and CF4) in comparison with the hydrogen bonding H2O ⋯ HF complex are studied by high-level ab initio calculations and electron topological atoms-in-molecules (AIM) analyses. The basis set superposition error corrections are importa...
The objective was to study their potential anticarcinogenic capacity in HeLa, HL-60 and U-937 tumour cell lines and to check whether the structural factors of the organic ligand may influence their biological activity. 2. Experimental 2.1. General procedures Human epithelial cervix carcinoma HeLa ...
The complexes with the empirical formula M(4-bipy)(ClCH2COO)2 × nH2O (where: 4-bipy=4,4'-bipyridine, L=ClCH2 COO–, M(II)=Mn, Co, Ni, Cu) were prepared an... D.,Czakis-Sulikowska,A.,... - 《Journal of Thermal Analysis & Calorimetry》 被引量: 19发表: 2000年 Hydrothermal...
These products have been identified as the previously reported compound Re2(CO)7(µ-H)[µ-η2-(CH2C)P(Ph)Me(o-C6H4)], 4 [3] formed in 11% yield by the decarbonylation of 3 and a CH activation on one of the phenyl rings on the phosphonio group at an ortho-position and ...