The results of experimental and theoretical studies of electron transfer in the chemistry of germylenes, stannylenes and their complexes are discussed. Experimental evidences for the existence of relatively stable radical ions of germylenes, stannylenes and their complexes were obtained. Electronic ...
ELECTRON TRANSFER IN THE REACTIONS OF GERMYLENES, STANNYLENES, AND THEIR COMPLEXES Main Group Metal ChemistryEgorov, Mikhail P.Nefedov, Oleg M.
Since the late 1940s, the field of electron transfer processes has grown enormously, both in chemistry and biology. The development of the field, experimentally and theoretically, as well as its relation to the study of other kinds of chemical reactions, presents to us an intriguing history, on...
Photochemical hydrogen atom transfer (HT) and electron transfer (ET) reactions of 1,4-anthraquinone (1,4-AQ) have been studied in acetonitrile at 295 K by means of CIDEP (chemically induced dynamic electron polarization) techniques and laser flash photolysis. It was shown on the basis of CIDEP...
Electron-transfer reactions in organic- chemistry. 2. An analysis of alkyl halide reduction by electron-transfer reagents on the basis of the Marcus theory. Acta Chem. Scand. B 36, 533-543.Eberson, L.: Electron-transfer reactions in organic chemistry. Adv. Phys. Org. Chem. 18, 79-185 ...
A. On the mechanism of possible influence of heteroatoms of nitrogen, boron and phosphorus in a carbon matrix on the catalytic activity of carbons in electron transfer reactions. Carbon 38, 1499–1503 (2000). Article CAS Google Scholar Martinez, U. et al. Fe–N–C catalysts: progress in ...
The following redox reactions investigated in this work are BChl 2 ∗ → BChl, BChl − → BPh, BPh − → Q A , and Q A → Q B . 2 Approach 2.1 Transmission Probability As a first attempt to understand the nature of biological electron transfer through the photosynthetic ...
However, their definition is not consistent with the associated free energy curves as functions of the reaction coordinate. The appropriate definition of the reaction coordinate and the associated free energy curves are presented.关键词: Solvents Electron transfer Free energy Polarization Transfer reactions...
Cytochrome c oxidase mediates the final step of electron transfer reactions in the respiratory chain, catalyzing the transfer between cytochrome c and the ... ML Tan,I Balabin,JN Onuchic - 《Biophysical Journal》 被引量: 138发表: 2004年 Electron transfer in genetically engineered proteins. The cy...