This follows an intriguing question: at an energy well below the CI, where the role of the adiabatic electronically excited state could be simply excluded, will there be observable effects due to the GP? Here we report a high-resolution CMB study on the H+HD → H2+D reaction at the ...
Particularly, the increase in chemical complexity makes the design of clusters for even local minimum configurations a time-consuming process. To tackle this challenge, an approach involving parametrizing the reaction coordinate and minimum energy path has been proposed38, however, leading to a low ...
While exploring various aspects of drying (drying rate, emission of volatile compounds), a better understanding of elementary reaction steps of the autoxidation process has been achieved. Studies regarding drier influence on autoxidation of EL and linseed oil have been performed [44], [45], [46]...
To summarize, studies focusing on empathy development during childhood are in line with Hoffman’s model [2], suggesting a shift from empathic distress (an automatic response) to empathic feeling (a thought-out emotional and cognitive reaction) as infants enter childhood. On the other hand, resea...
Furthermore, we reported a representative case of traumatic brain injury wherein thiopental administration dramatically affected oxidative-stress-related biomarkers. This study suggests that, in the future, sedatives containing thiopental may be redeveloped as an antioxidant therapy through further clinical ...
Structure formation of a single-stranded nucleic acid sequence x--from an unfolded, random coil structure c into the folded structure s--is a standard equilibrium reaction with temperature-dependent free energy MathML and equilibrium constant K T : MathML The number of possible secondary structures...
reverse reaction. Algorithms have been developed to enumerate both extreme pathways [6] and elementary modes [7] and these algorithm are all variants of the double description method [8], which enumerates all extreme rays of a polyhedral cone. The algorithms use as input a stoichiometric matrix...
A Model Reaction of an Elementary Step in the Fischer-Tropsch Synthesis:[C6Me6RuH(C2H4)PR3]+ from C6Me6Ru(CH3)2PR3doi:10.1002/anie.198300461Heidrun KletzinAnorganisch-chemisches Institut der Universität, Im Neuenheimer Feld 270, D-6900 Heidelberg 1 (Germany)Helmut Werner...
Cell-free expression has become a serious alternative to cell-based expression. In response to an increasing number of applications that require fast production of a large amount of proteins [1], new preparation methods and new reaction components are frequently proposed to improve protein productivity...
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