The exquisite ability of diethylaluminum benzenethiolate to efficiently discriminate between aldehydes and other carbonyl functions enables the chemoselective in situ reduction of ketones and methy...doi:10.1002/chin.201227063Gulluzar BastugLab. Chim. Org. Med., Univ. Cathol. Louvain, B-1348 Louvain...
Lipid peroxidation is sufficient to cause membrane damage, without the involvement of any specific pore-forming proteins, and leads to cell death5. The generation of secondary product aldehydes, including malondialdehyde (MDA), is a commonly used biochemical marker of lipid peroxidation5. The levels ...
In most species, individuals of the same sex share the same set of CHCs, which is referred to as CHC profile type13. Intriguingly, previous research found that females of the mason waspOdynerus spinipesare able to express two CHC profile types14. The two chemotypes (c1 and c2) qualitativel...
The concentration of ozone has been in a rising crescendo in the last decade while the fine particles (PM2.5) is gradually decreasing but still at a high l
It is known that the partially oxidation of alcohols to carbonyl compounds is one of the most significant transformations in organic synthesis and has attracted widespread interest [[18], [19], [20], [21], [22]]. The traditional selective oxidation of alcohols to corresponding aldehydes can be...
form with an apparently low pKa. We believe that Glu53 would also act as the general base in the THF-independent reaction converting β-hydroxyamino acids to the corresponding aldehydes and Gly. Conversely, none of the three histidine residues, although neutral, can act as a general base becau...
Pharmacokinetics (PK) is the study of the absorption, distribution, metabolism, and excretion (ADME) processes of a drug. Understanding PK properties is essential for drug development and precision medication. In this review we provided an overview of recent research on PK with focus on the follow...
The constituents of the wax layer are then synthesized from this VLCFA pool via two independent wax biosynthesis pathways in epidermal cells: (i) the acyl reduction pathway, generating primary alcohols and wax esters and (ii) the decarbonylation pathway, which produces aldehydes, alkanes, secondary...
Here, the CHO groups should represent oxygenated structures, such as, carboxylic acids, carbonyl compounds (ketones/aldehydes), alcohols, and esters and the CxHy groups represent hydrocarbon-like structures. In HULIS, the fractional contribution of CHO groups was on average 59% The contribution of ...
the MS surface. Thus, the highest inhibitory efficiency obtained was at 150 ppm of MBTC as 96.78%, and it was 95.09% for CBTC. The higher efficiency of MBTC is because of the presence of electron donor group –OCH3, imine, carbonyl groups and heterocyclic rings (Fig.1) which improved ...