Explores a novel iminoiodinane reagent for the copper-catalyzed aziridination of olefins, or alkenes. Reaction of sulfonamide with iodosobenzene diacetate in the presence of potassium hydroxide in the formation of the reagent; Preparation of N-[2-(trimethylsilyl)ethanesulfonyl]aziridines (N-Ses)-...
CheminformMetal-Free Aziridination of Styrene Derivatives with Iminoiodinane Catalyzed by a Combination of Iodine and Ammonium Iodide. KIYOKAWA K,KOSAKA T,MINAKATA S. Organic Letters . 2013Kiyokawa, K.; Kosaka, T.; Minakata, S. Metal-free aziridination of styrene derivatives with iminoiodinane ...
H. Dodd.PhI=NSes:A new iminoiodinane reagent for the copper-catalyzed aziridination of olefins. Journal of Organic Chemistry . 1999PhI=NSes:A new iminoiodinane reagent for the copper-catalyzed aziridination of olefins. P. Dauban,R. H. Dodd. Journal of Organic Chemistry . 1999...
Ton T M U,Tejo C,Tania S,et al.Iron (II)-catalyzed amidation of aldehydes with iminoiodinanes at room temperature and under microwave-assisted conditions.Journal of Organic Chemistry. 2011Ton T M U,Tejo C,Tania S,et al.Iron (II)-catalyzed amidation of aldehydes with iminoiodinanes at ...
Product NameN-tosyliMinobenzyliodinane CAS51608-60-7 MFC14H13NO2S MW259.32 EINECS MOL File51608-60-7.mol Chemical Properties Melting point108-115°C Boiling point415.7±38.0 °C(Predicted) Density1.15±0.1 g/cm3(Predicted) pka-4.71±0.50(Predicted) ...
Reaction of [N-(p-Toluenesulfonyl)imino]phenyliodinane with Trialkylboranes: Transformation of a Boron-Carbon Bond into a Nitrogen-Carbon BondYangR.-Y.DaiL.-X.ingentaconnectSynthesis Stuttgart
P. Detailed Structural Characterization of the Polyvalent Iminoiodinanes ArINTs (Ar = C6H5 or 2,4,6-Me3C6H2; Ts = SO2C6H4-4-Me) and the Aryldichloroiodinane 2,4,6-i-Pr3C6H2ICl2. Inorg. Chem. 1995, 34 (12), 3210-3214....
p> N -Acyliminoiodinanes were characterized for the first time by X-ray structural analysis. The ortho -methoxymethyl group and the carbonyl oxygen coordinate to the iodine atom of the iminoiodinane. Activation of the N -acyliminoiodinane was achieved by photoirradiation at 370nm, thereby ...
iminoiodinanesCatalytic insertion or addition of a metal-imido/nitrene species, generated from reaction of a transition-metal catalyst with iminoiodanes, to CH and CC bonds offers a convenient and atom economical method for the synthesis of nitrogen-containing compounds. Following this groundbreaking ...
MarilynM.Inorganic ChemistryMishra, A. K.; Olmstead, M. M.; Ellison, J. J.; Power, P. P. Detailed Structural Characterization of the Polyvalent Iminoiodinanes ArINTs (Ar = C6H5 or 2,4,6-Me3C6H2; Ts = SO2C6H4-4-Me) and the Aryldichloroiodinane 2,4,6-i-Pr3C6H2ICl2. Inorg...