Imines are organic compounds with a carbon-nitrogen double bond, while enamines have a carbon-nitrogen single bond adjacent to a carbon-carbon double bond.
The heats of formation of enamine radical cations are between 80 and 170 kJ mol 1 lower than the heats of formation of their imine counterparts, depending on the presence of substituents on the double bond and the nitrogen atom.doi:10.1016/S1387-3806(98)14145-3Jens Henriksen...
Under reactive conditions enamines (N-alkylation) are formed as the main products instead of the usually observed homologous imines (C-alkylation). The influence of the type of imine, solvent and alkylating agent on the mode of alkylation is discussed.G. J. Heiszwolf...
The influence of the electron-acceptor substituent on the thermal properties may be associated with the formation of the keto-enamine form, the presence of which would explain the observed regularities. This is beneficial when designing chemical structures of compounds for potential use in organic ...
The alkylation of imine anions formation of enaminesdoi:10.1002/recl.19700891112G. J. HeiszwolfH. KloosterzielRoyal Netherlands Chemical Society
STANFORTH S P. The Wittig reaction of fluorinated amides: Formation of enamine and imine tautomers[J]. Tetrahedron, 2001,57(9): 1833-1836.Stephen P.Stanforth. The Witting reaction of fluorinated amides:formation of enamine and imine tautomers[J].Tetrahedron 2001,9(9)....
Stephen P.Stanforth. The Witting reaction of fluorinated amides:formation of enamine and imine tautomers[J].Tetrahedron 2001,9(9).Stephen P Stanforth.The Wittig reaction of fluorinated amides: formation of enamine and imine tautomers[J]. Tetrahedron .2001(9)...
The Wittig reaction of fluorinated amides: Formation of enamine and imine tautomers[J]. Tetrahedron, 2001,57(9): 1833-1836.Stephen P.Stanforth. The Witting reaction of fluorinated amides:formation of enamine and imine tautomers[J].Tetrahedron 2001,9(9)....
Reactive intermediate deaminase (Rid) protein family is a recently discovered group of enzymes that is conserved in all domains of life and is proposed to play a role in the detoxification of reactive enamines/imines. UK114, the mammalian member of RidA subfamily, was identified in the early ...
It should be noted that—so far—the latter enzymes have been used to generate the RidA substrate, leaving some uncertainty about the nature of its actual substrate: the enamine or the imino acid. Therefore, the finding of activity with the product of the reaction of LAAO and DAAO and L...