Imine vs Enamine(111) Addition of Amine Derivatives(19) Wolff Kishner Reduction(20) Baeyer-Villiger Oxidation(20) Acid Chloride to Ketone(20) Nitrile to Ketone(20) Wittig Reaction(20) Ketone and Aldehyde Synthesis Reactions(10) 22. Carboxylic Acid Derivatives: NAS(463) 23. The ...
with the imine tautomersgenerally being the major reaction product. 3The formation of both enamine 5a,c and d and imine7a,c and d tautomers has been rationalised by themechanism shown in Scheme 2 in which the putativeoxaphosphetane intermediate 10 can give the productsin competing reaction ...
The Wittig reaction of fluorinated amides: Formation of enamine and imine tautomers[J]. Tetrahedron, 2001,57(9): 1833-1836.Stephen P.Stanforth. The Witting reaction of fluorinated amides:formation of enamine and imine tautomers[J].Tetrahedron 2001,9(9)....
Under reactive conditions enamines (N-alkylation) are formed as the main products instead of the usually observed homologous imines (C-alkylation). The influence of the type of imine, solvent and alkylating agent on the mode of alkylation is discussed.G. J. Heiszwolf...
The influence of the electron-acceptor substituent on the thermal properties may be associated with the formation of the keto-enamine form, the presence of which would explain the observed regularities. This is beneficial when designing chemical structures of compounds for potential use in organic ...
Imines are organic compounds with a carbon-nitrogen double bond, while enamines have a carbon-nitrogen single bond adjacent to a carbon-carbon double bond.
STANFORTH S P. The Wittig reaction of fluorinated amides: Formation of enamine and imine tautomers[J]. Tetrahedron, 2001,57(9): 1833-1836.Stephen P.Stanforth. The Witting reaction of fluorinated amides:formation of enamine and imine tautomers[J].Tetrahedron 2001,9(9)....
The alkylation of imine anions formation of enaminesdoi:10.1002/recl.19700891112G. J. HeiszwolfH. KloosterzielRoyal Netherlands Chemical Society
The heats of formation of enamine radical cations are between 80 and 170 kJ mol 1 lower than the heats of formation of their imine counterparts, depending on the presence of substituents on the double bond and the nitrogen atom.doi:10.1016/S1387-3806(98)14145-3Jens Henriksen...
P., ``The Wittig Reaction of Fluorinated Amides: For- mation of Enamine and Imine Tautomers,`` Tetrahedron, 57, 1833 Z2001..Stephen P.Stanforth. The Witting reaction of fluorinated amides:formation of enamine and imine tautomers[J].Tetrahedron 2001,9(9)....