Under reactive conditions enamines ( N -alkylation) are formed as the main products instead of the usually observed homologous imines ( C -alkylation). The influence of the type of imine, solvent and alkylating
STANFORTH S P. The Wittig reaction of fluorinated amides: Formation of enamine and imine tautomers[J]. Tetrahedron, 2001,57(9): 1833-1836.Stephen P.Stanforth. The Witting reaction of fluorinated amides:formation of enamine and imine tautomers[J].Tetrahedron 2001,9(9)....
Imine vs Enamine(0) Addition of Amine Derivatives(0) Wolff Kishner Reduction(0) Baeyer-Villiger Oxidation(0) Acid Chloride to Ketone(0) Nitrile to Ketone(0) Wittig Reaction(0) Ketone and Aldehyde Synthesis Reactions(0) 22. Carboxylic Acid Derivatives: NAS(0) 23. The Chemistry...
The influence of the electron-acceptor substituent on the thermal properties may be associated with the formation of the keto-enamine form, the presence of which would explain the observed regularities. This is beneficial when designing chemical structures of compounds for potential use in organic ...
STANFORTH S P. The Wittig reaction of fluorinated amides: Formation of enamine and imine tautomers[J]. Tetrahedron, 2001,57(9): 1833-1836.Stephen P.Stanforth. The Witting reaction of fluorinated amides:formation of enamine and imine tautomers[J].Tetrahedron 2001,9(9)....
The alkylation of imine anions formation of enaminesdoi:10.1002/recl.19700891112G. J. HeiszwolfH. KloosterzielRoyal Netherlands Chemical Society
Stephen P.Stanforth. The Witting reaction of fluorinated amides:formation of enamine and imine tautomers[J].Tetrahedron 2001,9(9).Stephen P Stanforth.The Wittig reaction of fluorinated amides: formation of enamine and imine tautomers[J]. Tetrahedron .2001(9)...
The heats of formation of enamine radical cations are between 80 and 170 kJ mol 1 lower than the heats of formation of their imine counterparts, depending on the presence of substituents on the double bond and the nitrogen atom.doi:10.1016/S1387-3806(98)14145-3Jens Henriksen...
Imines are organic compounds with a carbon-nitrogen double bond, while enamines have a carbon-nitrogen single bond adjacent to a carbon-carbon double bond.
Reactive intermediate deaminase (Rid) protein family is a recently discovered group of enzymes that is conserved in all domains of life and is proposed to play a role in the detoxification of reactive enamines/imines. UK114, the mammalian member of RidA subfamily, was identified in the early ...