Cannabinoids with high dipole moment () were poorly eluted in TLC, indicating a great interaction with the stationary phase. Their identifications could be conducted based on their distinct lipophilic characteristics () and the choice of a more polar solvent mix (). It is concluded that the DL ...
The solvation free energy (ΔGsol) is divided into the polar (ΔGGB) and non-polar (ΔGSurf) energy terms. SubstrateΔEELEΔEVDWΔEgasΔGSurfΔGGBΔGSolΔGbind kcal/mol kcal/mol kcal/mol kcal/mol kcal/mol kcal/mol kcal/mol UDP-Rha −200.21 −26.13 −226.35 −6.17 152.90 ...
The ECD determines polar localization of PknB, a step that may be required for proper activation of kinase signaling. Structure determination of PknB ECD using nuclear magnetic resonance, revealed an extended conformation of the PASTA domains in solution and suggested a ligand-dependent dimerization ...
Butler, J. A. V. and Ramchandani, C. N., 1935, The solubility of non-electrolytes. Part II. The influence of the polar group on the free energy of hydration of aliphatic compounds,J. Chem. Soc.280, 952–955. Google Scholar Butler, J. A. V., Ramchandani, C. N., and Thomson, ...
We earlier reported a simple specific test for detection of anti-ovarian antibodies in infertile women and identified number of specific molecular and cellular targets of which human heat shock protein 90-beta (HSP90 beta) was found to be the most immunodominant. The present study focuses on pred...
Solvent-accessible surface area calculations showed the compounds preferentially associated with binding sites where they penetrated into the MM core and shielded their non-polar atoms from solvent. Furthermore, with five of the six compounds the enantiomer with the most favorable free energy of MM ...
The synergistic solubilization capacity of corresponding polar solvent at a fixed composition and the nature of conductance plots in these RMs were markedly varied along with the composition of binary solvents (water and ACN at pure or mixed states) and the surfactant charge types (DDAB and AOT)....
The solvent composition and ratio of development system, the sample size, the fidelity, and precision were tested in order to estimate the effectiveness of separation of individual neutral and polar lipid classes and the quantitative reproducibility of the Iatroscan TLC-FID technique. GC-FID method,...
According to the present method, one or more metal salts of at least one iron group metal containing organic groups are dissolved and complex bound in at least one polar solvent with at least one complex former comprising functional groups in the form of OH or NR3 (R=H or alkyl). A ...
Solvent-accessible surface area calculations showed the compounds preferentially associated with binding sites where they penetrated into the MM core and shielded their non-polar atoms from solvent. Furthermore, with five of the six compounds the enantiomer with the most favorable free energy of MM ...