In this work we present a novel method to perform NUS HYSCORE experiments on commercial Bruker EPR spectrometers, along with a benchmark of modern reconstruction methods, and new processing software tools for NUS HYSCORE signals. All of this comes in the form of a free-software package: Hy...
spin echo (EPR)spin Hamiltonianstwo-dimensional spectraThe two-dimensional hyperfine-sublevel correlation (HYSCORE) experiment provides correlations between nuclear frequencies belonging to different MS manifolds. It is most useful for the assignment of electron spin echo envelope modulation (ESEEM) ...
HYperfine Sublevel CORrElation spectroscopy (HYSCORE) is one of the most widely applied EPR techniques for the investigation of hyperfine couplings in a wide range of spin systems; here, it is applied for the first time to a photoexcited triplet state. The analytical expressions describing the elec...
The structure of these defects was studied using advanced EPR spectroscopies. The x=0 glass exhibited a CW-EPR signal that was simulated by the parameters g1=2·0025, g2=2·0118, g3=2·0370 and AB2O3=(39·44, 43·45, 22·00 MHz). The CW-EPR spectra of the tellurium borate ...
HYperfine Sublevel CORrElation spectroscopy (HYSCORE) is one of the most widely applied EPR techniques for the investigation of hyperfine couplings in a wide range of spin systems; here, it is applied for the first time to a photoexcited triplet state. The analytical expressions describing the elec...
EPR-HYSCORE study of quinone binding in respiratory nitrate reductase: Molecular basis for the adaptation to anaerobiosis–aerobiosis transition1 alpha,25(OH)(2)-vitamin D-3Calcium uptakeGamma-glutamyl transpeptidasePKAPKCERK1 alpha,25-Dihydroxyvitamin D-3 (1,25D(3)) is critical...
Non-uniform HYSCORE: Measurement, processing and analysis with HyscoreanNon-uniform samplingNUSEPRHYSCORENUS HYSCOREmaxEntISTCAMERANon-uniform sampling (NUS) provides a considerable reduction of measurement time especially for multi-dimensional experiments. This comes at the cost of additional signal ...
CW-EPR, 1D-ESEEM, HYSCORE, pulsed ENDOR and SCF-HF calculations for the interpretation of defects in borate systemssimulationtest methodsthermal conductivitythermal propertiesGlasses of composition (100-x) mol% Bdoi:doi:10.1016/S0955-2219(00)00038-8Kordas, G...
Schweiger, Double nuclear coherence transfer (DONUT)-HYSCORE: a new tool for the assignment of nuclear fre- quencies in pulsed EPR experiments, J. Am. Chem. Soc. 120 (1998) 7020 - 7029.Goldfarb D, Kofman V, Libman J, Shanzer A, Rahmatouline R, Van Doorslaer S, Schweiger A. 1998....
In this work, we examined the influence of F114P, F114N, and N47S mutations on the electronic structure of the T1 copper center in azurin (Az) by studying the hyperfine couplings of CβH2protons of Cys112 using the two-dimensional (2D) pulsed EPR technique HYSCORE (hyperfine sublevel ...