HYperfine Sublevel CORrElation spectroscopy (HYSCORE) is one of the most widely applied EPR techniques for the investigation of hyperfine couplings in a wide range of spin systems; here, it is applied for the first time to a photoexcited triplet state. The analytical expressions describing the ...
spin echo (EPR)spin Hamiltonianstwo-dimensional spectraThe two-dimensional hyperfine-sublevel correlation (HYSCORE) experiment provides correlations between nuclear frequencies belonging to different MS manifolds. It is most useful for the assignment of electron spin echo envelope modulation (ESEEM) ...
HYperfine Sublevel CORrElation spectroscopy (HYSCORE) is one of the most widely applied EPR techniques for the investigation of hyperfine couplings in a wide range of spin systems; here, it is applied for the first time to a photoexcited triplet state. The analytical expressions describing the elec...
Non-uniform sampling NUS EPR HYSCORE NUS HYSCORE maxEnt IST CAMERA 1. Introduction In EPR spectroscopy, multi-dimensional experiments, foremost the two-dimensional hyperfine sublevel correlation (HYSCORE) experiment, play a pivotal role in the study of hyperfine couplings in a variety of electron-nu...
Double nuclear coherence transfer (DONUT)-HYSCORE: A new tool for the assignment of nuclear frequencies in pulsed EPr experiments Van Doorslaer, and A. Schweiger, Double nuclear coherence transfer (DONUT)- HYSCORE: A new tool for the assignment of nuclear frequencies in pulsed EPR experiments, ...
EPR spectroscopysemiconductorstitaniatitaniumReduced states in TiO2: 17O hyperfine sublevel correlation spectroscopy was used to monitor the local environment of stable Ti3+ ions generated in a 17O-enriched polycrystalline TiO2 (rutile) sample (see picture). A hyperfine interaction of about 8MHz is ...
HYSCORE spectroscopy has clarified conflicting results in previous electron paramagnetic resonance (EPR) and electron nuclear double resonance (ENDOR) studies and found clear differences between the two CuA azurins. Specifically, a hyperfine coupling AN⊥ of 15.3 MHz was determined for the first time ...
Non-uniform samplingNUSEPRHYSCORENUS HYSCOREmaxEntISTCAMERANon-uniform sampling (NUS) provides a considerable reduction of measurement time especially for multi-dimensional experiments. This comes at the cost of additional signal processing steps to reconstruct the complete signal from the experimental ...
An EPR/HYSCORE, Mossbauer, and resonance Raman study of the hydrogenase maturation enzyme HydF: A model for N-coordination to [4Fe-4S] clusters. J. Biol. Inorg. Chem. 2014, 19, 75-84. [CrossRef] [PubMed]Berggren G, Garcia-Serres R, Brazzolotto X, Cleman...
The structure of Cu(II) complex 3 formed within the course of a stereoselective Diels-Alder reaction was investigated by EXAFS, CW-EPR at X- and W-band, HY... C Bolm,M Martin,G Gescheidt,... - 《Journal of the American Chemical Society》 被引量: 137发表: 2003年 1D- and 2D-ESEEM...