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The hyperfine structure due to 193Ir (I=3/2) and 191Ir (I=3/2) is well resolved enabling determination of magnetic (h5/2) and nuclear electric quadrupole (eQq0) hyperfine parameters for the [17.6]2.5 (v=0) and X2.5 (v=0) states. The dominant configuration of the ground state is...
[270]. Also used in the fit were the v = 1–0 heterodyne IR data from Hinz et al. [271] and the very accurate data from Saupe et al. [272]. Show abstract The spectrum of nitric oxide between 1700 and 2100 cm-1 1995, Journal of Molecular Spectroscopy Show abstract Heterodyne frequen...
The higher J rotational lines of both transitions are observed to split into closely spaced doublets resulting from quadrupole hyperfine structure caused by the I=3/2 nuclear spin in 191Ir and 193Ir. Analysis of the spectra shows that the hyperfine structure is concentrated in the two excited ...
The cross effect is found to be present for p- as well as s-polarization of the IR beam. This effect however exactly vanishes for p-polarization and 45-degrees incidence angle. This prediction, together with the calculated magnitude of the effect, has been verified experimentally for the case...
IR SPECTRAISOTOPE LABELING2,2'-PYRIDIL2,2'-PYRIDIL-O-18VIBRATIONAL ASSIGNMENTThe effect of discrete rotational jumps on the EPR lineshape of single crystals is discussed from the relaxation matrix viewpoint. A theory for isolated paramagnetic centers of spin S = 1 2 and hyperfine interaction is...
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