Hydrogen bonding in HCN…HF, HCN…HCl, CH3CN…HF and CH3CN…HC1; an ab initio SCF-MO studydoi:10.1016/0378-4487(81)80002-7Large scale gaussian orbital SCF-MO results are reported for the title hydrogen-bonded complexes. Calculated R(N…H) distances, hydrogen bond dissociation energies and...
Localized molecular orbital studies of hydrogen bonding in hydrogen fluoride (HF2-), hydrogen chloride (HCl2-), hydrogen fluoride chloride (HFCl-), monoprotonated chlorine, and hydrogen fluoride (HF2) moleculestheory, structureNo abstract is available for this article.doi:10.1002/chin.198445001SAN...
Hydrogen bonding is the attractive interaction that occurs between a hydrogen atom bound in a molecule to an electronegative atom such as oxygen or nitrogen and another electronegative atom from a different molecule (intermolecular) or even from the same molecule (intramolecular). ...
we examine hydrogen bonding in the H2S dimer, in comparison with the well-studied water dimer, in unprecedented detail. We record a mass-selected IR spectrum of the H2S dimer in superfluid helium nanodroplets. We are able to resolve a rotational substructure in...
Does Hi have hydrogen bonding? The molecules of HCl, HBr,HI do not form a hydrogen bond. Can HCl and hi form hydrogen bonds? HCl is not classified as being able to form hydrogen bonds. This is due to its difference in electronegativity being below the level needed to qualify... ...
Hydrogen bonding, as a relatively weak inter- or intra-molecular interaction, plays a crucial role not only in chemical compounds, biological structure, function, and conformational dynamics but also in chemical reactions such as proton transfer and catalysis. Therefore, hydrogen bonding has always bee...
Hydrogen Bonding Properties of the Complexes of Formaldehyde and its Derivatives with HF and HCldoi:10.1007/s007060200008The complexes of formaldehyde and some of its derivatives with HF and HCl were investigated at HF/6-311 + +G** and MP2/6-311 + +G** levels of theory. ...
Although hydrogen bonding is thought to be limited to the elements \({\rm{N}},{\rm{ O}}\), and \({\rm{F}}\), some compounds containing \({\rm{Cl}}\) may also participate in hydrogen bonding. The hydrogen bond’s energy ranges from \(10\) to \(100\, {\rm{ kJ\, mo}}...
1.(Elements & Compounds) a colourless pungent corrosive gas obtained by the action of sulphuric acid on sodium chloride: used in making vinyl chloride and other organic chemicals. Formula: HCl 2.(Elements & Compounds) an aqueous solution of hydrogen chloride; hydrochloric acid ...
Some Basic Concepts in Chemistry 15 P– Block Elements 2 States of Matter 16 D– and F – Block Elements 3 Atomic Structure 17 Co-ordination Compounds 4 Chemical Bonding and Molecular Structure 18 Environmental Chemistry 5 Chemical Thermodynamics 19 Purification and Characterisation of Organic Compound...